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Dynamics of polar solvation: Route to single exponential relaxation via translational diffusion

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Abstract

A microscopic theoretical calculation of time-dependent solvation energy shows that the solvation of an ion or a dipole is dominated by a single relaxation time if the translational contribution to relaxation is significant.

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Authors and Affiliations

  1. Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012, Bangalore, India

    Biman Bagchi & Amalendu Chandra

Authors
  1. Biman Bagchi
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  2. Amalendu Chandra
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Contribution No. 545 from the Solid State and Structural Chemistry Unit

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Bagchi, B., Chandra, A. Dynamics of polar solvation: Route to single exponential relaxation via translational diffusion. Proc. Indian Acad. Sci. (Chem. Sci.) 100, 353–357 (1988). https://doi.org/10.1007/BF02840546

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