Skip to main content
Log in

Novel preparation and XPS analysis of V2O5 xerogel

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

The V2O5 sol was fabricated by ultra-fast quenching. The vanadium with low valence (V4+) was found in V2O5 xerogel films by XPS analysis. The technology of oxygen top-blown was applied to analyze the XPS spectrum difference of V2O5 xerogel when the powder of V2O5 was melting in air or in oxygen atmosphere. The results show that the different melting atmosphere has certain influences on the chemical valence of V2O5 xerogel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Le D B, Passerini S, Guo J, Ressler J, Owens B B, Smyrl W H. High Surface Area V2O5 Xerogel Intercalation Electrodes.J. Electrochem. Soc., 143,(7):2099–2104

  2. Chung S K, Chmilenko N A, Borovykov A Ya, Lee S H. Rechargeable Lithium Cells with Modified Vanadium Oxide Cathodes.Journal of Power Sources, 1999,84:6–11

    Article  CAS  Google Scholar 

  3. Mott N F.Metal-Insulator Transition. London: Taylor and Francis, 1974

    Google Scholar 

  4. Livage J, Beteille F, Roux C, Chatry M, Davidson P. Sol-gel Synthesis of Oxide Materials.Acta Mater., 1998,46(3):734–750

    Article  Google Scholar 

  5. Vivier V, Farcy J, Pereira-Ramos J. Elactrochemical Lithium Insertion in Sol-gel Crystalline Vanadium Pentoxide Thin Films.Electrochimica Acta, 1998,44:831–839

    Article  CAS  Google Scholar 

  6. Haber J, Witko M, Tokart R, Vanadium pentoxide I. Structures and Properties.Applied Catalysis A: Gerneral, 1997,152:3–22

    Article  Google Scholar 

  7. Chen W, Xu Q, Mai L Q,et al. Effect of Modification by Poly (ethylene—oxide) on Reversibility of Insertion/extraction of Li+ ion in V2O5 Xerogel films.J. Mater. Chem., 2002,12:1926–1930

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

ZHU Quan-yao: Born in 1968

Funded by the National Natural Science Foundation of China (No. 50172036, No. 59802009)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Quan-yao, Z., Wen, C., Qing, X. et al. Novel preparation and XPS analysis of V2O5 xerogel. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 18, 27–29 (2003). https://doi.org/10.1007/BF02838451

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02838451

Key Words

Navigation