Abstract
A new compound of mono-6-(1′-benzo-aza-15-crown-5)-2, 3, 6-permethyl-β-cyclodextrin (BA-15C5-PM-CD) was synthesized. The structure was determined to be coincide with our anticipation by spectroscopy. As a stationary phase for capillary gas chromatography, excellent separation for enantioners and positional isomers was achieved.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Ronald Breslow, Anthony W, Czarnik. Transamination by pyridoxamine selectively attached at C-3 in β-cyclodextrin.J Am Chem Soc, 1983,105: 1390–1391
Lu Tian Bao, Wu Cheng Tai. The study on aza crown ether.Organic Chemistry, 1985,5(3): 312–314 (in Chinese)
Matsui Y, Okimoto A. The binding and catalytic properties of a positively charged cyclodextrin.Bull of Chem Soc of Jpn, 1978,51: 3030–3034
Zeng Zhaorui, Zhou Zhiping, Wu Caiying,et al. Retention and Thermodynamic properties of solutes on two types β-cyclodextrin derivatiue stationary phases.Analytical Chemistry, 1997,25(8):874–878 (in Chinese)
Wu Cai Ying, Wang Cheng Ming, Zeng Zhao Rui,et al. Preparation and characteristics of a crown ether polysiloxane stationary phase for capillary gas chromatography.Anal Chem, 1990,62: 968–971
Author information
Authors and Affiliations
Additional information
Supported by the National Natural Science Foundation of China(No. 29475201)
Liu Min: born in 1974, Graduate student
Rights and permissions
About this article
Cite this article
Min, L., Zhaorui, Z., Yuqiang, D. et al. The synthesis of a new cyclodextrin-crown ether chiral stationary phase and application in gas chromatography. Wuhan Univ. J. Nat. Sci. 3, 337–340 (1998). https://doi.org/10.1007/BF02829988
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02829988