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Anion transfer in ZrO2 and HfO2 bicrystals containing 12 mol % Y2O3

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Abstract

The oxygen-ionic conduction in the YSZ|YSZ and YSZ|YSH bicrystals, where YSZ and YSH are single-crystalline solid solutions of, respectively, ZrO2 and HfO2 with 12 mol % Y2O3 are studied using the impedance method. Bicrystals consist of two single crystals separated by a common intercrystalline boundary. The direction of the applied electrical field is chosen perpendicular to the intercrystalline boundary. The oxygen-ion transfer in the bicrystals is determined primarily by the transport processes in the bulk single crystals. This is associated with a fast exchange by oxygen vacancies between single crystals at the intercrystalline boundary.

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References

  1. Dragoo, A.L., Chiang, C.K., and Franklin, A.D.,Solid State Ionics, 1982, vol. 7, p. 249.

    Article  CAS  Google Scholar 

  2. El Adham, K. and Hammou, A.,Solid State Ionics, 1983, vols. 9-10, p. 905.

    Article  Google Scholar 

  3. Badwal, S.P.S.,Solid State Ionics, 1992, vol. 52, p. 23.

    Article  CAS  Google Scholar 

  4. Filal, M., Petot, C., Mokchah, M.,et al., Solid State Ionics, 1995, vol. 80, p. 27.

    Article  CAS  Google Scholar 

  5. Trubelja, M.F. and Stubican, V.S.,J. Am. Ceram. Soc., 1991, vol. 74, no. 10, p. 2489.

    Article  CAS  Google Scholar 

  6. Tzalenchuk, A.Ya., Regel, V.R., and Stepantsov, E.A.,Mater. Sci. Forum, 1990, vols. 62–64, p. 359.

    Google Scholar 

  7. Kingery, W.D., Pappis, J., Doty, M.E., and Hill, D.C.,J. Am. Ceram. Soc., 1959, vol. 42, no. 8, p. 393.

    Article  CAS  Google Scholar 

  8. Ivanov-Shits, A.K., Sorokin, N.I., Fedorov, P.P., and Sobolev, B.P.,Fiz. Tverd. Tela, 1983, vol. 25, p. 1748.

    CAS  Google Scholar 

  9. Dygas, J.R.,Ph. D. Thesis, Evanston: Northwestern Univ., 1986.

    Google Scholar 

  10. Bauerle, J.E.,J. Phys. Chem. Solids, 1969, vol. 30, p. 2657.

    Article  CAS  Google Scholar 

  11. Velle, O.J., Norby, T., and Kofstad, P.,Solid State Ionics, 1991, vol. 47, p. 161.

    Article  CAS  Google Scholar 

  12. Cole, K.S. and Cole, R.H.,J. Chem. Phys., 1941, vol. 9, p. 341.

    Article  CAS  Google Scholar 

  13. Ukshe, E.A. and Bukun, N.G.,Tverdye elektrolity (Solid Electrolytes), Moscow: Nauka, 1977.

    Google Scholar 

  14. Norby, T. and Hartmanova, M.,Solid State Ionics, 1993, vol. 67, p. 57.

    Article  CAS  Google Scholar 

  15. Stupina, N.N. and Katsnel’son, A.A.,Kristallografiya, 1989, vol. 34, p. 1502.

    CAS  Google Scholar 

Download references

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  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, 117333, Moscow, Russia

    N. I. Sorokin

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  1. N. I. Sorokin
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Sorokin, N.I. Anion transfer in ZrO2 and HfO2 bicrystals containing 12 mol % Y2O3 . Russ J Electrochem 36, 319–322 (2000). https://doi.org/10.1007/BF02827977

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  • DOI: https://doi.org/10.1007/BF02827977

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