Abstract
Convective instability of K4[Fe(CN)6] + K3[Fe(CN)6] solution in an electrochemical cell with plane horizontal electrodes is analyzed theoretically. A diagram for nonequilibrium phase transitions is constructed. Conditions for the rise of a Rayleigh-Benard instability and the oscillatory convective instability are determined.
Similar content being viewed by others
References
Grigin, A.P. and Davydov, A.D.,Elektrokhimiya, 1998, vol. 34, p. 1237.
Grigin, A.P. and Davydov, A.D.,Elektrokhimiya, 1997, vol. 33, p. 871.
Grigin, A.P. and Davydov, A.D.,J. Electroanal. Chem., 1998, vol. 450, p. 7.
Prigogine, I.,From Being to Becoming, San Francisco: Freeman, 1980.
Grigin, A.P. and Davydov, A.D.,Dokl. Ross. Akad. Nauk, 1998, vol. 358, p. 202.
Gershuni, G.Z. and Zhukhovitskii, E.M.,Konvektivnaya ustoichivost’ neszhimaemoi zhidkosti (The Convective Stability of Incompressible Liquids), Moscow: Nauka, 1972.
Kantorovich, L.V. and Krylow, V.M.,Approximate Methods of Higher Analysis, New York: Wiley, 1964.
Spravochnik po elektrokhimii (A Handbook on Electrochemistry), Sukhotin, A.M., Ed., Leningrad: Khimiya, 1981.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Grigin, A.P., Davydov, A.D. Convective instability of ferro-ferricyanide solution in plane interelectrode space. Russ J Electrochem 36, 286–291 (2000). https://doi.org/10.1007/BF02827971
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02827971