Journal of Electronic Materials

, Volume 22, Issue 10, pp 1195–1198 | Cite as

Chemistry of electron doped Ln2−xCexCuO4 superconductors

  • A. Manthiram
  • Y. T. Zhu
Special Issue Paper


The electron doped Ln2−xCexCuO4 (Ln=lanthanide) oxides have intergrowth structures consisting of superconductively active CuO2 sheets alternating with inactive (Ln, Ce)2O2 fluorite layers along the c-axis. Stabilization of such intergrowth structures requires bond length matching across the intergrowth interface. The bond length matching criterion causes a monotonic decrease in the Ce solubility limit from x=0.24 to x=0.15 as the size of Ln3+ decreased from Ln=La0.5Nd0.5 to Ln=Gd. Annealing in N2 atm of Ln2−xCexCuO4 at temperatures above 900°C creates oxygen vacancies and the number of vacancies decreases with increasing Ce content. The value of x at which a semiconductor to superconductor transition occurs in Ln2−xCexCuO4 increases with decreasing size of Ln3+ due to an increasing Madelung energy caused by a decreasing Cu−O bond length.

Key words

Bond length mismatch cerium solubility limit electron doped superconductors Ln2−xCexCuO4 superconductors oxygen content 


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Copyright information

© The Minerals, Metals & Materials Society 1993

Authors and Affiliations

  • A. Manthiram
    • 1
  • Y. T. Zhu
    • 1
  1. 1.Center for Materials Science and Engineering, ETC 9.104The University of Texas at AustinAustin

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