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Tempered martensite embrittlement in a high purity steel

  • Mechanical Behavior
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Abstract

This paper reports a study of tempered martensite embrittlement in a low alloy steel. Even though this material would ordinarily be considered high purity (0.004 wt pct S and 0.004 wt pct P) the 40 wppm S are sufficient to cause the embrittlement. The results show that this embrittlement will only occur if sulfur is present on the grain boundaries in its elemental form. It it is precipitated along the grain boundaries as chromium sulfides, no embrittlement trough is observed. However, the fracture energy of all samples is reduced. This is because microvoid coalescence occurs at these grain boundary precipitates in the same manner as is observed in overheated steels.

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References

  1. C. L. Briant and S. K. Banerji:Int. Met. Rev., 1978, vol. 23, p. 164.

    CAS  Google Scholar 

  2. S. K. Banerji, C. J. McMahon, Jr., and H. C. Feng:Met. Trans. A., 1978, vol. 9A, p. 237.

    Article  CAS  Google Scholar 

  3. C. J. McMahon, Jr.:Grain Boundaries in Engineering Materials, J. L. Walteret al. eds., 4th Bolton Landing Conf. Baton Rouge, Claitor’s Publ. Div. 1975, p. 525.

  4. L. J. Klinger, W. J. Barnett, R. P. Frohmberg, and A. R. Troiano:Trans. ASM, 1954, vol. 46, p. 1557.

    Google Scholar 

  5. J. M. Capus and G. Meyer:Metallurgia, 1960, vol. 62, p. 133.

    Google Scholar 

  6. J. M. Capus and G. Meyer:J. Iron Steel Inst., 1958, vol. 196, p. 255.

    Google Scholar 

  7. J. M. Capus and G. Meyer:J. Iron Steel Inst., 1963, vol. 201, p. 53.

    Google Scholar 

  8. B. R. Banerjee:J. Iron Steel Inst., 1965, vol. 203, p. 166.

    Google Scholar 

  9. E. B. Kula and A. A. Anctii:J. Mater., 1969, vol. 4, p. 817.

    Article  CAS  Google Scholar 

  10. C. L. Briant and S. K. Banerij:Met. Trans. A., 1979, vol. 10A, pp. 123–26.

    Article  CAS  Google Scholar 

  11. G. Thomas,Met. Trans. A., vol. 9A, p. 439.

  12. R. O. Ritchie:Met. Trans. A., 1978, vol. 9A, p. 1039.

    Google Scholar 

  13. J. E. King, R. F. Smith, and J. F. Knott:Fracture 1977—ICF4, D. M. R. Taplin, ed., vol. 2, p. 279. Waterloo, University of Waterloo Press, 1977.

    Google Scholar 

  14. B. C. Edwards and E. A. Little: Metallurgy Division, AERE, Harwell, U.K., presented at BNES Conf. Ferritic Steels for Fast Reactors, London, May 30–June 2, 1977.

  15. R. G. Rowe, C. L. Briant, and F. Bacon:Proc. Microbeam Soc. Conf., vol. 12, pp. 72A–72E, 1977.

  16. C. Pichard, J. Rieu, and C. Goux:Mem. Sci. Rev. Met., vol. 70, 1973, p. 13.

    CAS  Google Scholar 

  17. B. J. Schultz and C. J. McMahon, Jr.:Met. Trans., 1973, vol. 4, p. 2485.

    Article  Google Scholar 

  18. J. Q. Clayton: Ph. D. Thesis, Cambridge University, U.K., 1977.

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Briant, C.L., Banerji, S.K. Tempered martensite embrittlement in a high purity steel. Metall Trans A 10, 1151–1155 (1979). https://doi.org/10.1007/BF02811660

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