Abstract
This paper reports a study of tempered martensite embrittlement in a low alloy steel. Even though this material would ordinarily be considered high purity (0.004 wt pct S and 0.004 wt pct P) the 40 wppm S are sufficient to cause the embrittlement. The results show that this embrittlement will only occur if sulfur is present on the grain boundaries in its elemental form. It it is precipitated along the grain boundaries as chromium sulfides, no embrittlement trough is observed. However, the fracture energy of all samples is reduced. This is because microvoid coalescence occurs at these grain boundary precipitates in the same manner as is observed in overheated steels.
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C. L. Briant and S. K. Banerji:Int. Met. Rev., 1978, vol. 23, p. 164.
S. K. Banerji, C. J. McMahon, Jr., and H. C. Feng:Met. Trans. A., 1978, vol. 9A, p. 237.
C. J. McMahon, Jr.:Grain Boundaries in Engineering Materials, J. L. Walteret al. eds., 4th Bolton Landing Conf. Baton Rouge, Claitor’s Publ. Div. 1975, p. 525.
L. J. Klinger, W. J. Barnett, R. P. Frohmberg, and A. R. Troiano:Trans. ASM, 1954, vol. 46, p. 1557.
J. M. Capus and G. Meyer:Metallurgia, 1960, vol. 62, p. 133.
J. M. Capus and G. Meyer:J. Iron Steel Inst., 1958, vol. 196, p. 255.
J. M. Capus and G. Meyer:J. Iron Steel Inst., 1963, vol. 201, p. 53.
B. R. Banerjee:J. Iron Steel Inst., 1965, vol. 203, p. 166.
E. B. Kula and A. A. Anctii:J. Mater., 1969, vol. 4, p. 817.
C. L. Briant and S. K. Banerij:Met. Trans. A., 1979, vol. 10A, pp. 123–26.
G. Thomas,Met. Trans. A., vol. 9A, p. 439.
R. O. Ritchie:Met. Trans. A., 1978, vol. 9A, p. 1039.
J. E. King, R. F. Smith, and J. F. Knott:Fracture 1977—ICF4, D. M. R. Taplin, ed., vol. 2, p. 279. Waterloo, University of Waterloo Press, 1977.
B. C. Edwards and E. A. Little: Metallurgy Division, AERE, Harwell, U.K., presented at BNES Conf. Ferritic Steels for Fast Reactors, London, May 30–June 2, 1977.
R. G. Rowe, C. L. Briant, and F. Bacon:Proc. Microbeam Soc. Conf., vol. 12, pp. 72A–72E, 1977.
C. Pichard, J. Rieu, and C. Goux:Mem. Sci. Rev. Met., vol. 70, 1973, p. 13.
B. J. Schultz and C. J. McMahon, Jr.:Met. Trans., 1973, vol. 4, p. 2485.
J. Q. Clayton: Ph. D. Thesis, Cambridge University, U.K., 1977.
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Briant, C.L., Banerji, S.K. Tempered martensite embrittlement in a high purity steel. Metall Trans A 10, 1151–1155 (1979). https://doi.org/10.1007/BF02811660
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DOI: https://doi.org/10.1007/BF02811660