Abstract
The χ,T phase diagram of (NH4I)x(KI)1−x has been determined using neutron diffraction experiments and dielectric spectroscopy. At low temperatures and with decreasing χ, the sequence γ, β, ε and glass phase has been detected. The critical concentration χc≈0.55 separates the glassy phase with frozen-in orientational disorder from the ε phase which reveals long-range orientational order. Close to χc our experiments reveal evidence for two subsequent glass transitions.
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References
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