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Synthesis and crystal and molecular structure of the complex Zn(Phen)(S2COC4H9-i)2

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Abstract

A mixed-ligand complex Zn(Phen)(S2COC4H9-i)2 was synthesized. The single crystals of the complex were studied by X-ray diffractometry. The crystals are orthorhombic, a = 20.053(2), b = 19.272(2), c = 13.203(1) A, Vcdl = 5102.5(8) Å3, space group Pcab, Z = 8, dcalc = 1.416 g/cm3, R = 0.059. The structure consists of monomeric molecules in which the coordination polyhedron of the central Zn atom is a distorted octahedron (CN = 6). An analysis of molecular packing and intermolecular distances showed that the molecules related by the symmetry center are involved in pronounced intermolecular interactions.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    L. A. Glinskaya, T. G. Leonova, V. N. Kirichenko, R. F. Klevtsova & S. V. Larionov

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  1. L. A. Glinskaya
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  2. T. G. Leonova
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  3. V. N. Kirichenko
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  4. R. F. Klevtsova
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  5. S. V. Larionov
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Deceased.

Translated fromZhumal Struktumoi Khimii, Vol. 38, No. 1, pp. 142–147, January–February, 1997.

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Glinskaya, L.A., Leonova, T.G., Kirichenko, V.N. et al. Synthesis and crystal and molecular structure of the complex Zn(Phen)(S2COC4H9-i)2 . J Struct Chem 38, 116–120 (1997). https://doi.org/10.1007/BF02768816

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  • DOI: https://doi.org/10.1007/BF02768816

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