Skip to main content
SpringerLink
Log in

Metal-protective coatings for graphite-containing crucibles based on oxide-fluoride mixtures

  • Research
  • Published:
Refractories and Industrial Ceramics Aims and scope

Abstract

Special features of phase transformations in the system SiO2−Al2O3−CaF2 are considered regarding the synthesis of metal-protective coatings for graphite-containing crucibles. It is shown that the compound CaAl2Si2O8 obtained in the oxide-fluoride mixture Al2Si2O7+SiO2+CaF2 is stable toward aluminum alloys. The use of metal-protective coatings increases the stability of graphite-containing crucibles more than 4-fold.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. L. Phillips and J. E. Hanlon,J. Am. Ceram. Soc.,46(9), 447–450 (1963).

    Article  CAS  Google Scholar 

  2. A. S. Berezhnoi,Milticomponent Systems of Oxides [in Russian], Naukova Dumka, Kiev (1970).

    Google Scholar 

  3. L. P. Ruzinov and B. S. Gulyanitskii,Equilibrium Transformations in Metallurgical Reactions [in Russian], Metallurgiya, Moscow (1975).

    Google Scholar 

  4. A. I. Snegirev, E. Ya. Gimpel’man, and V. I. Pivovarova,Ogneupory, No. 10, 23–27 (1987).

    Google Scholar 

  5. A. I. Snegirev, A. A. Fotiev, and D. S. Rutman,Zh. Neorg. Khim.,32(2), 456–459 (1987).

    CAS  Google Scholar 

  6. N. A. Toropov, V. P. Barzakovskii, V. V. Lapin, et al.,Phase Diagrams of Silicate Systems: Handbook [in Russian], Nauka, Leningrad (1972).

    Google Scholar 

  7. O. Kubashevskii and S. B. Alkock,Metallurgical Thermochemistry, Pergamon Press, Oxford (1979).

    Google Scholar 

  8. A. I. Snegirev, A. S. Smetanin, and V. I. Pivovarova, “Refractory coating, USSR Patent No. 1823870,”Byull. Otkryt. Izobret., No. 23, 53 (1993).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid-State Chemistry of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russia

    A. I. Snegirev & B. V. Slobodin

Authors
  1. A. I. Snegirev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. V. Slobodin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Ogneupory i Tekhnicheskaya Keramika, No. 1, pp. 22–24, January, 1997.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Snegirev, A.I., Slobodin, B.V. Metal-protective coatings for graphite-containing crucibles based on oxide-fluoride mixtures. Refract Ind Ceram 38, 27–29 (1997). https://doi.org/10.1007/BF02768231

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02768231

Keywords

Search

Navigation