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Binary and ternary complexes involving manganese(II), 2,2’-bipyridine and halide or thiocyanate ions inN,N-dimethylformamide

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Abstract

Ternary complexation involving the manganese(II) ion, 2,2’-bipyridine (bipy), and halide (chloride, bromide) or pseudohalide (thiocyanate) ions has been studied by precise titration calorimetry inN,N -dimethylformamide (DMF) at 298K. All the titration curves are explained well in terms of formation of mononuclear complexes of the type [MnXm(bipy)n](2-m) + (X = CI, Br or SCN), and the formation of [MnCl(bipy)]+, [MnCl2(bipy)], [MnCl(bipy)2]+ and [MnCl2(bipy)2] has been established in the chloride system, [MnBr(bipy)]+, [MnBr2(bipy)], [MnBr(bipy)2]+ in the bromide system, and [Mn(NCS)(bipy)]+, [Mn(NCS)2(bipy)], [Mn(NCS)3(bipy)]-, [Mn(NCS)(bipy)2]+, and [Mn(NCS)2(bipy)2] in the thiocyanate system. The data were analyzed on the basis of the thermodynamic parameters for the binary MnlIbipy and MnII-X (X = Cl, Br and SCN) systems, the latter being determined in previous work. The formation constants, reaction enthalpies, and entropies of the ternary complexes were extracted. The thermodynamic parameters thus obtained are discussed in comparison with those of the corresponding systems of other transition metal(II) ions.

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References

  1. M. A. Kahn and D. G. Tuck,Acta Crystallogr., Sect. C 40, 60 (1984).

    Article  Google Scholar 

  2. G. A. Barclay, B. F. Hoskins, and C. H. L. Kennard,J Chem. Soc. 5691 (1963).

  3. W. D. Harrison, B. J. Hathaway, and D. Kennedy,Acta Crystallogr. Sect. B 35, 2301 (1979).

    Article  Google Scholar 

  4. F. S. Stephens and P. A. Tucker,J. Chem. Soc, Dalton Trans. 2293 (1973).

  5. J. Keiser, G. Brauner, F. A. Schroder, I. F. Taylor, and S. E. Ramussen,J. Chem. Soc. Dalton Trans. 1974, 1490.

  6. B. J. Hathaway and A. Murphy,Acta Crystallogr., Sect. B 36, 295 (1980).

    Article  Google Scholar 

  7. M. A. Kahn and D. G. Tuck,Acta Crystallogr., Sect. B 37, 1409 (1981).

    Article  Google Scholar 

  8. E. C. Constable,Coord. Chem. Rev. 58, 1 (1984).

    Article  CAS  Google Scholar 

  9. M. N. Hughes,Coord. Chem. Rev. 37, 297 (1981).

    Article  CAS  Google Scholar 

  10. C. W. Reimann, S. Block, and A. Perioff,Inorg. Chem. 5, 1185 (1966).

    Article  CAS  Google Scholar 

  11. A. Walsh, B. Walsh, B. Murphy, and B. J. Hathaway,Acta Crystallogr. Sect B 37, 1512 (1981).

    Article  Google Scholar 

  12. E. D. McKenzie,Coord. Chem. Rev. 31, 783 (1971).

    Google Scholar 

  13. M. Ignaczak and G. Andrijewski,Zhur. Neorg. Khim. 35, 1710 (1990).

    CAS  Google Scholar 

  14. Y. Abe and G. Wada,Bull. Chem. Soc. Jpn. 60, 1936 (1987).

    Article  CAS  Google Scholar 

  15. M. Emara and M. Bahr,Bull. Soc. Chim. Fr. I, 25 (1983).

    Google Scholar 

  16. Y. Abe and G. Wada,Bull. Chem. Soc. Jpn. 54, 3334 (1981).

    Article  CAS  Google Scholar 

  17. H. Sigel, B. Fisher and B. Prijs,J. Am. Chem. Soc. 99, 4489 (1977).

    Article  CAS  Google Scholar 

  18. D. Hague and S. Martin,J. Chem. Soc. Dalton Trans. 254 (1974).

  19. R. L. Davies and K. W. Dunning,J. Chem. Soc. 4168 (1905).

  20. G. Anderegg,Helv. Chim. Acta 46, 1833, 2813 (1963).

    Article  CAS  Google Scholar 

  21. G. Anderegg,Helv. Chim. Acta 46, 2397 (1963).

    Article  CAS  Google Scholar 

  22. G. Atkinson and J. Bauman,Inorg. Chem. 1, 900 (1962).

    Article  Google Scholar 

  23. H. Irving and D. Mellor,J. Chem. Soc. 5222, 5237 (1962).

    Google Scholar 

  24. C. Luca,Bull. Soc. Chim. Fr. 2556 (1967).

  25. D. D. Perrin and V. S. Sharma,J. Inorg. Nuclear Chem. 28, 1271 (1966).

    Article  CAS  Google Scholar 

  26. S. C. Lahiri and S. Aditya,Z Phys. Chem. (Frankfurt) 41, 173 (1964).

    CAS  Google Scholar 

  27. H. Irving and D. H. Miller,J. Chem. Soc. 3457 (1955).

  28. K. Lal and R. P. Agarwal,J. Less-Common Metals 12, 269 (1967).

    Article  CAS  Google Scholar 

  29. W. A. E. McBryde,A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10-Phenanthroline and 2, 2-Bipyridyl and Related Compounds, IUPAC Chemical Data Series No. 17, (Pergamon Press, 1978).

  30. S. Ishiguro, B. G. Jeliazkova, and H. Ohtaki,Bull. Chem. Soc. Jpn. 58, 1143 (1985).

    Article  CAS  Google Scholar 

  31. S. Ishiguro, K. Ozutumi, and H. Ohtaki,Bull. Chem. Soc. Jpn. 60, 531 (1987).

    Article  CAS  Google Scholar 

  32. S. Ishiguro, K. Ozutumi, L. Nagy, and H. Ohtaki,Bull. Chem. Soc. Jpn. 60, 1961 (1987).

    Article  Google Scholar 

  33. K. Ozutumi and S. Ishiguro,J. Chem. Soc. Faraday Trans. 86, 271 (1990).

    Article  Google Scholar 

  34. S. Ishiguro and K. Ozutumi,Inorg. Chem. 29, 1117 (1990).

    Article  CAS  Google Scholar 

  35. S. Ishiguro, L. Nagy, and H. Ohtaki,Bull. Chem. Soc. Jpn. 60, 2053 (1987).

    Article  CAS  Google Scholar 

  36. S. Ishiguro, L. Nagy, and H. Ohtaki,Bull. Chem. Soc. Jpn. 60, 2865 (1987).

    Article  CAS  Google Scholar 

  37. S. Ishiguro, K. Ozutumi, L. Nsgy, and H. Ohtaki,J. Chem. Dalton Trans. 655, (1989).

  38. S. Ishiguro and K. Ozutumi,Bull. Chem. Soc. Jpn. 62, 2392 (1989).

    Article  CAS  Google Scholar 

  39. S. Ishiguro, K. Ozutumi, M. Miyauchi, and H. Ohtaki,Inorg. Chem. 28, 3258 (1989).

    Article  CAS  Google Scholar 

  40. S. Ishiguro, K. Ozutumi, and A. Ohtaki,Bull. Chem. Soc. Jpn. 63, 3030 (1990).

    Article  CAS  Google Scholar 

  41. S. Ishiguro, M. Miyauchi, and K. Ozutumi,J. Chem. Soc. Dalton Trans. 2035 (1990).

  42. H. Suzuki and S. Ishiguro,Netsu Sokutei 15, 152 (1988).

    CAS  Google Scholar 

  43. S. Ishiguro, K. Ozutumi, and H. Ohtaki,J. Chem. Soc. Faraday Trans. I 84, 2409 (1988).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, 812-81, Higashiku, Fukuoka, Japan

    Morito Komiya & Shin-ichi Ishiguro

  2. Department of Electronic Chemistry, Tokyo Institute of Technology at Nagatsuta, Yokohama 226, Midori-ku, Japan

    Satoshi Yoshida

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  1. Morito Komiya
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  2. Satoshi Yoshida
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  3. Shin-ichi Ishiguro
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Komiya, M., Yoshida, S. & Ishiguro, Si. Binary and ternary complexes involving manganese(II), 2,2’-bipyridine and halide or thiocyanate ions inN,N-dimethylformamide. J Solution Chem 26, 997–1010 (1997). https://doi.org/10.1007/BF02768056

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  • DOI: https://doi.org/10.1007/BF02768056

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