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Group contributions to the infinite dilution partial molar volumes of alkanes, alcohols, and glycols in polar organic solvents

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Abstract

Densities of binary mixtures of polar organic solvents with alcohols were measured at 25‡C. The solvents studied were N,N-dimethylformamide, dimethylsulfoxide, and formamide while alcohols were butanol, pentanol, hexanol, and 1,4-butanediol. Density measurements of hydrocarbons (from pentane to dodecane and some heptane isomers) + N,N-dimethylformamide were also performed. From these data the apparent molar volumes of alcohols and hydrocarbons as functions of concentration were calculated. The standard partial molar volumes were obtained by extrapolation to infinite dilution and are discussed in terms of group contributions.

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Authors and Affiliations

  1. Department of Chemistry, University of Bari, 4 Trav. 200 Re David, 70126, Bari, Italy

    Americo Inglese & Fabio Mavelli

  2. Department of Physical Chemistry, University of Palermo, 26 Via Archirafi, 90123, Palermo, Italy

    Rosario De Lisi & Stefania Milioto

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  1. Americo Inglese
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  2. Fabio Mavelli
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  3. Rosario De Lisi
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  4. Stefania Milioto
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Inglese, A., Mavelli, F., De Lisi, R. et al. Group contributions to the infinite dilution partial molar volumes of alkanes, alcohols, and glycols in polar organic solvents. J Solution Chem 26, 319–336 (1997). https://doi.org/10.1007/BF02768002

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  • DOI: https://doi.org/10.1007/BF02768002

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