Abstract
A mechanism of photocatalytic synthesis of chlorohydrins from olefins and peroxo complexes of titanium (IV) is proposed. It consists of formation of radical-containing complexes, their reactions with olefins, and decomposition of the α-oxides obtained by hydrogen chlorides.
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Additional information
L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prosp. Nauki, 252039 Kiev, Ukraine. Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 33, No. 1, pp. 17–21, January–February, 1997.
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Kuchmii, S.Y., Minaev, B.F., Korzhak, A.V. et al. Mechanism of reactions of photocatalytic synthesis of chlorohydrins. Theor Exp Chem 33, 16–20 (1997). https://doi.org/10.1007/BF02764737
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DOI: https://doi.org/10.1007/BF02764737