Abstract
The thermal and mechanical stability of some high-strength ceramic materials from partially stabilized ZrO2 manufactured from various domestic and imported powders, including coprecipitated, sol-gel, and hydrothermal ones, with the use of CIP and sintering is considered. The thermal stability is tested under conditions close to the operating ones, i.e., under long-duration holds at 1000 and 1550°C and in water quenching. The mechanical stability is determined in impact-erosion wear and under combined loads of high pressure and multiple indentations by solid particles. It is shown that all the materials undergo degradation of various degrees but those most durable under normal conditions (hydrothermal and sol-gel materials, ceramics manufactured from imported press powders) are least stable. They have widely fluctuating properties under cyclic high-temperature loads, endure 900-1400°C, and withstand a pressure of at most 1.0-2.0 GPa in an abrasive, just like standard corundum ceramics; however, they are characterized by maximum wear resistance. At the same time, an original material from commercial coprecipitated PSZ powder has quite different features; its thermal stability allows it to withstand repeated quenchings from 1550°C in water, and the mechanical strength can attain 2.6-2.8 GPa, exceeding the strength of quenched tool steels in similar situations. Due to its refractoriness (2700°C) and chemical stability this material is the most versatile in operating under extreme conditions.
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References
G. Ya. Akimov, I. Yu. Prokhorov, I. V. Gorelik, et al., “The role of cold isostatic pressing in forming the properties of ceramics based on ZrO2 obtained from ultradisperse powders,”Ogneupory, No.2, 12-19(1995).
I. Yu. Prokhorov, G. Ya. Akimov, V. M. Timchenko, and A. D. Vasil’ev, “Cold isostatic pressing as a method for manufacturing high-strength ceramic materials based on ZrO2,”Ogneup. Tekh. Keram., No. 8, 12-17 (1997).
I. Yu. Prokhorov, “Zirconia materials from coprecipitated powders,”Ogneup. Tekh. Keram., No. 12, 2–6 (1997).
M. Yosimura, T. Noma, K. Kavabata, and S. Somiya, “Effect of the temperature and high pressure of water on the low-temperature destabilization of tetragonal zirconia stabilized by yttrium oxide,”Nippon Seramikkusu Kekay Galuszyutsu Rombuksi,96(3), 265–270 (1988).
Chen San-Yuan and Lu Hong-Yang, “Sintering of 3 mol.% Y2O3-TZP and its fracture ageing treatment,”J. Mater. Sci.,23(4), 1195–1200(1988).
R. L. K. Matsumoto, “Strength recovery in degraded yttriadoped tetragonal zirconia polycrystals,”J. Am. Ceram. Soc.,68(8), 213 (1985).
Lu Hong-Yang, Chen San-Yuan, “Low-temperature ageing oft- ZrO2 polycrystals with 3 mol.% Y2O3,”J. Am. Ceram. Soc.,70(8), 537 -541 (1987).
J. L. Drummond, “In vitro ageing of yttria-stabilized zirconia,”J. Am. Ceram. Soc.,72(4), 675–676 (1989).
T. V. Chusovitina, Yu. I. Komolikov, and S. I. Stepanov, “Stability of properties of ceramic materials based on partially stabilized zirconia,”Steklo Keram., No. 11-12, 33-34 (1982).
T. T. Lepisto and T. A. Mantyla, “A model for structural degradation of Y-TZP ceramics in humid atmosphere,”Ceram. Eng. Sci. Prod.,10(7-8), 1362 (1989).
D. L. Davidson, J. B. Campbell, and J. Lankford, “Fatigue crack growth through partially stabilized zirconia at ambient and elevated temperatures,”Acta Met. Mater.,39(6), 1319–1330 (1991).
M. T. Hernandez, J. R. Jurado, P. Duran, and J. L. Fierro, “Subeutectoid degradation of yttria-stabilized tetragonal zirconia polycrystal and ceria-doped yttria-stabilized tetragonal zirconia polycrystal ceramics,”J. Am. Ceram. Soc.,74(6), 1254 -1258(1991).
K. Kuroda, H. Saka, S. Iio, et al., “Tetragonal-to-monoclinic transformation in ZrO2-Y2O3 ceramics,” in:Martensit. Transform.: Proc. Int. Conf. (ICOMAT-86), Nara, Aug. 26–30, 1986,Sendai (1987), pp. 1161-1166.
K. Sato and M. Shimada, “Control of tetragonal-to-monoclinic phase transformation of yttria partially stabilized zirconia in hot water,”J. Mater. Sci.,20 (11), 3988–3992 (1985).
Advanced Zirconia Ceramics for Your Toughest Applications, ICI Ceramics Inc., Ausburn CA (1992).
D. R. Clarke and F. Adar, “Measurement of the crystallographically transformed zone produced by fracture in ceramics containing tetragonal zirconia,”J. Am. Ceram. Soc.,65(6), 284–288(1982).
G. N. Morscher, P. Pirouz, and A. N. Heuer, “Temperature dependence of hardness in yttria-stabilized zirconia single crystals,”J. Am. Ceram. Soc.,74(3), 491–500 (1991).
J. Martinez-Fernandez, M. Jimenez-Melendo, A. Domingerz-Rodrigues, and A. H. Heuer, “Microindentation-induced transformation in 3.5 mol.%-yttria-partially-stabilized zirconia single crystals,”J. Am. Ceram. Soc.,74(5), 1071–1081 (1991).
O. N. Grigor’ev, G. S. Krivoshei, N. A. Stel’mashenko, et al., “Phase transformations in mechanical treatment and properties of surface layers in zirconia ceramics,”Poroshk. Metallurg., No. 5, 30-33(1991).
L. K. Lenz and A. N. Heuer, “Stress-induced transformation during subcritical crack growth in partially stabilized zirconia,”J. Am. Ceram. Soc.,65(11), 192–194 (1982).
D. B. Marshall and M. R. James, “Reversible stress-induced martensitic transformation in ZrO2,”J. Am. Ceram. Soc.,69(3), 215–217(1986).
D. L. Davidson, J. B. Campbell, and J. Lankford, “Fatigue crack growth through partially stabilized zirconia at ambient and elevated temperatures,”Acta Met. Mater.,39(6), 1319–1330 (1991).
C. J. Howorth, W. E. Lee, W. M. Rainforth, and P. F. Messer, “Contamination rates from Ceand Y-TZP ball milling media,”Br. Ceram. Trans, and J.,90(1), 18–21 (1991).
D. S. Rutman, Yu. S. Toropov, S. Yu. Pliner, et al. (eds.),Zirconia High-Refractory Materials [in Russian], Metallurgiya, Moscow (1985).
P. J. Whalen, F. Reidinger, S. T. Correale, and J. Marti, “Yttria migration in Y-PSZ during high-temperature annealing,”J. Mater. Sci.,22(12), 4465–4469 (1987).
A. M. Gavrish, B. Ya. Sukharevskii, E. I. Zoz, and P. P. Krivoruchko, “Effect of impurities on the decomposition of solid solutions based on zirconia,”Izv. Akad. Nauk SSSR, Neorg. Mater.,5(6), 1103–1106(1969).
M. Riihle and A. G. Evans, “High toughness ceramics and ceramic composites,”Progr. Mater. Sci.,33, 85–167 (1989).
M. J. Ready and A. N. Heuer, “Annealing of test specimens of high-toughness magnesia-partially-stabilized zirconia,”J. Am. Ceram. Soc.,71(1), 2–6 (1988).
M. V. Swain, R. S. Garvie, and R. J. Hannink, “Influence of thermal decomposition on the mechanical properties of magnesiastabilized cubic zirconia,”J. Am. Ceram. Soc.,66(5), 358 -362 (1983).
G. Ya. Akimov, V. M. Timchenko, and N. G. Labinskaya, “Effect of the method of stabilization of the tetragonal phase on the mechanical properties of polycrystalline zirconia,”Fiz. Tverd. Tela,37, Issue 7, 2146–2161 (1995).
E. G. Subbarao, H. S. Maiti, and K. K. Srivastava, “Martensitic transformation in zirconia,”Phys. Stat. Sol. (a),21(1), 9–40 (1974).
D. F. Kalinovich, L. I. Kuznetsova, and É. T. Denisenko, “Zirconia: properties and use (a review of foreign literature),”Poroshk. Met., No. 11, 98-103 (1987).
A. G. Gashchenko, G. A. Gogotsi, A. G. Karaulov, et al., “A study of the thermal stability and mechanical characteristics of zirconia-based materials,”Problemy Proch., No. 6, 76 -80 (1974).
N. A. Toropov, V. P. Barzakovskii, et al.,Phase Diagrams of Silicate Systems, Issue 1, Binary Systems [in Russian], Nauka, Moscow (1969).
J. K. Lancaster, Y. A. H. Marshall, and A. G. Atrins, “The role of water in the wear of ceramics,”J. Phys. D.,25(1A), A205-A211 (1992).
G. G. Gnesin (ed.),Ceramic Tool Materials [in Russian], Tekhnika, Kiev (1991).
Y. M. Chen, S. C. Pavy, and B. Rigaut, “Effets de l’humidite sur le comportement des ceramiques AI2O3, Si3N4 et PSZ en frottement á grande vitresse sur acier,”Mater. Techn.,79, Num. spec., 40–44(1991).
R. H. J. Hannink, M. J. Murray, and H. G. Scott, “Friction and wear of partially stabilized zirconia: basic science and practical applications,”Wear,100, 355–366 (1984).
H. Hasegawa, “Surface structure of Y-TZP,”J. Jpn. Inst. Metals,52(6), 603–608 (1988).
A. G. Dobrovol’skii and P. I. Koshelenko (eds.),Abrasion Strength of Materials, A Reference Book [in Russian], Tekhnika, Kiev (1989).
“Ceramic wear-resistant parts expected to experience rapid growth,”Interceram., 41(6), 435 (1992).
“Nilcra advanced ceramics have long life,”Austral. Mining, 79(12), 24-25 (1987).
“Orders secured for ceramic brake piston,”Ceram. Ind. Int., 101(1088), 6 (1991).
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Prokhorov, I.Y., Akimov, G.Y. & Timchenko, V.M. Stability of structural materials based on ZrO2 . Refract Ind Ceram 39, 189–197 (1998). https://doi.org/10.1007/BF02764271
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DOI: https://doi.org/10.1007/BF02764271