Skip to main content
SpringerLink
Log in

The adsorption of salts of trimethyl-substituted sulfonium, selenonium, and telluronium on iron in sulfuric acid solutions

  • Published:
Protection of Metals Aims and scope Submit manuscript

Abstract

Adsorption of trimethyl-substituted sulfonium, selenonium, and telluronium iodides on the armco-iron in 0.5 M H2SO4 is studied by the capacitance method. The compounds studied proved to be highly efficient inhibitors of the cathodic hydrogen evolution. The contribution of organic cations and anions to the total retardation of the cathodic process is evaluated. Some assumptions on the adsorption mechanism are proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Reshetnikov, S.M.,Ingibitory kislotnoi korrozii metallov (Inhibitors of Acid Corrosion of Metals), Leningrad: Khimiya, 1986.

    Google Scholar 

  2. Antropov, L.I., Pogrebova, I.S., and Dremova, G.I.,Zashch. Met., 1971, vol. 7, no. 1, p. 2.

    Google Scholar 

  3. Afanas’ev, B.N., Skobochkina, Yu.P., and Serdyukova, G.I.,Elektrokhimiya, 1989, vol. 25, no. 10, p. 1365.

    CAS  Google Scholar 

  4. Reshetnikov, S.M., Kichigin, V.I., and Burmistr, M.V.,Zashch. Met., 1982, vol., 18, no. 6, p. 927.

    CAS  Google Scholar 

  5. Aramaki, K., Hagiwara, M., and Nishihara, H.,J. Electrochem. Soc., 1988, vol. 135, no. 6, p. 1364.

    Article  CAS  Google Scholar 

  6. Troquet, M. and Pagetti, J.,Werkst. Korros., 1983, vol. 34, no. 11, p. 557.

    Article  CAS  Google Scholar 

  7. Pletnev, M.A., Reshetnikov, S.M., Ternavtseva, I.V.,et al., Zashch. Met., 1990, vol. 26, no. 1, p. 144.

    CAS  Google Scholar 

  8. Pletnev, M.A.,Cand. Sci. (Chem.) Dissertation, Moscow, 1989.

  9. Reshetnikov, S.M., Pletnev, M.A., Shabanova, I.N.,et al., Zashch. Met., 1987, vol. 23, no. 3, p. 499.

    CAS  Google Scholar 

  10. Ternavtseva, I.V., Pletnev, M.A., and Reshetnikov, S.M.,ibid.,, 1994, vol. 30, no. 6, p. 624.

    CAS  Google Scholar 

  11. Reshetnikov, S.M., Ternavtseva, I.V., and Ionov, L.B., Abstracts of Papers,2 Vsesoyuznaya shkola-seminar (2nd All-Union School-Seminar), Izhevsk: Udmurt. Gos. Univ, 1991, p. 117.

    Google Scholar 

  12. Shein, A.B., Aitov, R.G., Beloglazova, N.N.,et al., RF Patent 2030400,Byull. Izobret., 1995, no. 7.

  13. Shein, A.B., Aitov, R.G., Beloglazova, N.N.,et al., RF Patent 2059018,Byull. Izobret, 1996, no. 12.

  14. Nedugov, A.N., Pavlova, N.N., Shalimov, A.V.,et al., RF Patent 2032665,Byull. Izobret., 1995, no. 10.

  15. Nedugov, A.N., Pavlova, N.N., Shalimov, A.V.,et al., RF Patent 2032666,Byull. Izobret., 1995, no. 10.

  16. Egorov, L.Ya. and Novosel’skii, I.M.,Elektrokhimiya, 1971, vol. 7, no. 7, p. 988.

    CAS  Google Scholar 

  17. Organic Electrochemistry. An Introduction and a Guide, Baizer, M., Ed., New York: Dekker, 1973.

    Google Scholar 

  18. Mairanovskii, S.G., Stradyn’, Ya.P., and Bezuglyi, V.D.,Polyarografiya v organicheskoi khimii (Organic Polarography), Leningrad: Khimiya, 1975.

    Google Scholar 

  19. Horner, L. and Lund, H., inOrganic Electrochemistry. An Introduction and a Guide, Baizer, M., Ed., New York: Dekker, 1973.

    Google Scholar 

  20. Sheinkman, A.K., Kapkan, L.M., Gakh, L.G.,et al., Dokl. Akad. Nauk SSSR, 1970, vol. 193, no. 2, p. 366.

    CAS  Google Scholar 

  21. Becker, G.,Einfuehrung in die Elektronentheorie organischer Reaktionen, Berlin: Deutscher Verlag der Wissenschaften, 1974.

    Google Scholar 

  22. Kuprin, V.P. and Nechaev, E.A.,Zashch. Met., 1986, vol. 22, no. 4, p. 599.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Perm State University, ul. Bukireva 15, 614600, Perm, Russia

    A. B. Shein, V. I. Kichigin & A. N. Nedugov

Authors
  1. A. B. Shein
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Kichigin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. N. Nedugov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shein, A.B., Kichigin, V.I. & Nedugov, A.N. The adsorption of salts of trimethyl-substituted sulfonium, selenonium, and telluronium on iron in sulfuric acid solutions. Prot Met 36, 490–494 (2000). https://doi.org/10.1007/BF02764098

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02764098

Keywords

Search

Navigation