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Crystal and molecular structure of the monoclinic modification of Mn(S2CO-i-C3H7)2(2,2’-bipy)

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Abstract

The crystal and molecular structure of modification II of the Mn(S2CO-i-C3H7)2(2,2’-Bipy) complex was determined from X-ray diffraction data (“Syntex P21” diffractometer, CuKα radiation, 1603 F(hkl), R = 0.0446). The crystals are monoclinic,a = 23350(3),b = 9.325(1),c = 22.030(2) å, Β = 106.98(1)‡,V = 4587.7 å3, Z =8, d calc = 1.394 g/cm3, space group C2/c. The structure consists of monomeric molecules in which the manganese atom has a distorted octahedral environment (4S + 2N). The orthorhombic and monoclinic modifications of the complex are compared with respect to the molecular geometry and packing.

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Authors and Affiliations

  1. institute of inorganic chemistry, siberian branch, russian academy of sciences, USSR

    R. F. Klevtsova & L. A. Glinskaya

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  1. R. F. Klevtsova
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  2. L. A. Glinskaya
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Translated fromZhurnal Strukturnoi Khimii, Vol. 38, No. 5, pp. 960–966, September-October, 1997.

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Klevtsova, R.F., Glinskaya, L.A. Crystal and molecular structure of the monoclinic modification of Mn(S2CO-i-C3H7)2(2,2’-bipy). J Struct Chem 38, 805–810 (1997). https://doi.org/10.1007/BF02763895

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