Skip to main content
SpringerLink
Log in

Crystal and molecular structures of bis-(5-methyl-5-butoxy-hexanedionato-2,4) Copper(II) and bis-(2,2-dimethyl-5-cyclohexyl-pentanedionato-3,5) Copper(II)

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Two new volatile complexes of Cu(II) containing methoxy groups were studied in a combined X-ray diffraction investigation of the mono- (KUMA automatic diffractometer, MoKα radiation) and polycrystals (DRON-3M, CuKα radiation). The structures are molecular and consist of the trans-complexes of bis-(5-methyl-5-butoxy-hexanedionato-2,4)copper(II), C22H38CuO6, and bis-(2,2-dimethyl-5-cyclohexyl-pentanedionato-3,5) Copper(II), C28H46CuO6. The crystal data of C22H38CuO6: a = 8.939(1), b = 8.887(2), c = 8.326(1) å, α = 107.92(2), Β = 108.15(1), γ = 85.52(2)‡, space group P1,V= 597.9(2) å3, Z = 1, dx = 1.283 g/cm3. The crystal data of C28H46CuO6: a = 18.625(3), b = 16.126(2), c= 13.613(3) å, Β = 132.19‡, space group P21/n, V= 3029.3(9) å3, Z = 4, dx= 1.189 g/cm3. In both cases, the square planar environment of the Cu atom with Cu...O distances of 1.90 å is completed by interactions with two carbon atoms of the terminal groups of the two neighboring molecules at Cu...C distances of 3.66 å (average).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. S. Zanina, S. I. Shergina, I. E. Sokolov, et al.,Sib. Khim. Zh., No. 4, 69–73 (1991).

  2. S. A. Gromilov, I. A. Baidina, P. A. Stabnikov, et al.,Zh. Neorg. Khim.,33, No. 5, 104–107 (1991).

    Google Scholar 

  3. S. A. Gromilov, I. A. Baidina, P. A. Stabnikov, and S. A. Prokhorova,Zh. Strukt. Khim.,35, No. 6, 169–175 (1994).

    Google Scholar 

  4. I. A. Baidina, S. A. Gromilov, P. A. Stabnikov, et al.,ibid.,33, No. 5, 141–144 (1992).

    CAS  Google Scholar 

  5. I. A. Baidina, S. A. Gromilov, P. A. Stabnikov, and A. D. Vasiliev,ibid.,38, No. 1, 143–149 (1997).

    Google Scholar 

  6. S. A. Gromilov, I. A. Baidina, and G. I. Zharkova,ibid.,38, No. 5, 946–953 (1997).

    Google Scholar 

  7. S. A. Gromilov and V. I. Lisoyvan,Zavod. Labor.,54, No. 7, 57–58 (1988).

    CAS  Google Scholar 

  8. I. A. Baidina, P. A. Stabnikov, I. K. Igumenov, et al.,Koordinats. Khim.,15, No. 6, 763–768 (1989).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, USSR

    I. A. Baidina, S. A. Gromilov, P. A. Stabnikov & A. D. Vasiliev

Authors
  1. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Gromilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. A. Stabnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. D. Vasiliev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromZhurnal Strukturnoi Khimii, Vol. 38, No. 5, pp. 954–959, September-October, 1997.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Baidina, I.A., Gromilov, S.A., Stabnikov, P.A. et al. Crystal and molecular structures of bis-(5-methyl-5-butoxy-hexanedionato-2,4) Copper(II) and bis-(2,2-dimethyl-5-cyclohexyl-pentanedionato-3,5) Copper(II). J Struct Chem 38, 799–804 (1997). https://doi.org/10.1007/BF02763894

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02763894

Keywords

Search

Navigation