Skip to main content
SpringerLink
Log in

Redetermination of the crystal structure of potassium peroxodisulfate (K2S2O8)

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal structure of potassium peroxodisulfate was determined. The crystals are triclinic, a =5.115(1),b =7.034(2), c =5.505(1) å, α =106.32(2),gb =90.18(2), γ =106.12(2)‡, Vcell = 181.90(7) å3, space group PĪ, Z =1, dcalc =2.468 g/cm 3 [“Syntex P21,” λCuKα, 994 reflections measured in a whole sphere to 2Τmax =114‡, including 496 independent reflections (Rint = 0.0571), R(F) = 0.0391, wR(F2) = 0.0933 for 486 Fhkl > 4Σ(F)]. An absorption correction (Μ = 171.37 cm−1) was applied taking into account the shape and size of the crystal using data about face indices. The representative of the single crystal was proven by comparing the experimental and calculated diffractograms. The geometrical characteristics of S2O 28 : S-O 1.645(2), S = 0 1.421(3)-1.429(2), O-O 1.495(5) å, S-O-O 106.2(2)‡.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Marshall,J. Chem. Soc.,59, 771–780 (1891).

    CAS  Google Scholar 

  2. Yu. A. Serguchev and I. P. Beletskaya,Usp. Khim.,49, No. 12, 2257–2285 (1980).

    CAS  Google Scholar 

  3. M. C. R. Symons and S. B. Barnes,J. Chem. Soc. (A), 2000–2002 (1970).

  4. A. Reuveni, Z. Luz, and B. L. Silver, J. Magn.Reson.,12, 109–118 (1973).

    CAS  Google Scholar 

  5. V. A. Radtsig and A. A. Politov,Kinet. Katal,26, No. 1, 42–50 (1985).

    CAS  Google Scholar 

  6. A. I. Lapshin, A. E. Borodaevskii, and S. S. Batsanov,Khim. Vys. énerg.,4, No. 2, 154–159 (1970).

    CAS  Google Scholar 

  7. M. Barbooti and F. Jasim,Thermochim. Acta,16, 402–406 (1976).

    Article  CAS  Google Scholar 

  8. A. I. Lapshin and K. A. Tleulieva,Zh. Prikl. Spektrosk.,24, No. 4, 677–682 (1976).

    CAS  Google Scholar 

  9. K. D. Cleaver and J. E. D. Davies,J. Raman Spectrosc.,9, No. 6, 376–380 (1980).

    Article  CAS  Google Scholar 

  10. R. C. Keen, Z.Kristallogr.,91, 129–135 (1935).

    Google Scholar 

  11. Strukturbericht, Vol. 3, Akademische Verlagsgesellschaft, Leipzig (1937), p. 501.

  12. R. W. G. Wyckoff,Crystal Structures, Vol. 3, Wiley (1965), p. 463.

  13. P. Groth,Chemische Kristallographie, Vol. 2, Leipzig (1908), pp. 724–725.

  14. A. Gerstecker, H. Möller, and A. Reis,Z. Kristallogr.,66, 421–423 (1927).

    Google Scholar 

  15. Powder Diffraction File, International Center for Diffraction Data, PA (1982).

  16. Powder Diffraction File, Alphabetical Index, Inorganic Phases, Vol. 3, International Center for Diffraction Data, PA (1983), p. 1018.

  17. R. G. Gerr, A. I. Yanovskii, and Yu. T. Struchkov,Kristallografiya,28, No. 5, 1029–1030 (1983).

    Google Scholar 

  18. G. M. Sheldrick,Acta Crystallogr.,A46, 467–473 (1990).

    CAS  Google Scholar 

  19. G. M. Sheldrick,ibid.,A49 (Suppl.), C53 (1993).

  20. A. F. Wells,Structural Inorganic Chemistry, Clarendon Press, Oxford (1986), p. 501.

    Google Scholar 

  21. W. H. Zachariasen and R. C. L. Mooney,Z. Kristallogr.,88, 63–81 (1934).

    CAS  Google Scholar 

  22. B. K. Sivertsen and H. Sorum,ibid.,130, 449–460 (1969).

    CAS  Google Scholar 

  23. N. V. Podberezskaya, T. S. Yudanova, S. A. Magarill, et al.,Zh. Strukt. Khim.,32, No. 6, 137–150 (1991).

    CAS  Google Scholar 

  24. N. V. Podberezskaya, T. S. Yudanova, S. A. Magarill, et al., in:Problems in Crystal Chemistry [in Russian], Nauka, Moscow (1990), pp. 82–98.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid State Chemistry, Siberian Branch, Russian Academy of Sciences, USSR

    D. Yu. Naumov, A. V. Virovets, N. V. Podberezskaya, P. B. Novikov & A. A. Politov

  2. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, USSR

    D. Yu. Naumov, A. V. Virovets, N. V. Podberezskaya, P. B. Novikov & A. A. Politov

  3. Novosibirsk State University, Russia

    D. Yu. Naumov, A. V. Virovets, N. V. Podberezskaya, P. B. Novikov & A. A. Politov

Authors
  1. D. Yu. Naumov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Virovets
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Podberezskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. B. Novikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Politov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromZhurnal Strukturnoi Khimii, Vol. 38, No. 5, pp. 922–929, September-October, 1997.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Naumov, D.Y., Virovets, A.V., Podberezskaya, N.V. et al. Redetermination of the crystal structure of potassium peroxodisulfate (K2S2O8). J Struct Chem 38, 772–778 (1997). https://doi.org/10.1007/BF02763891

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02763891

Keywords

Search

Navigation