Abstract
The method of pulse high-current cathode luminescence is used to study the Bi2O3-Er2O3-CeO2 system at room temperature in air. New luminescence centers associated presumably with cation vacancies and an anion vacancy are determined in systems containing CeO2. The luminescence parameters are shown to behave nonmonotonically with variation of the composition of the system. It is assumed that an abrupt change in these parameters at a certain composition of the substance corresponds to a phase transformation.
Similar content being viewed by others
References
S. G. Mikhailov, V. V. Osipov, and V. V. Solomonov, “Pulse-periodic cathode luminescence of minerals,”Zh. Tekh. Fiz.,63(2), 52–64 (1993).
V. I. Solomonov, “On the mechanism of excitation of pulse cathode luminescence,” in:Detection of Ionizing Radiation [in Russian], UGTU, Ekaterinburg (1996), pp. 85–97.
D. A. MacDonall and P. W. M. Jacobs, “On the lattice parameter of some sesquioxides with fluorite structure,”J. Solid State,B4(2), 183–193.
A. N. Tarashchan,Luminescence of Minerals [in Russian], Naukova Dumka, Kiev (1978).
V. N. Strekalovskii, S. F. Pal’guev, and Yu. M. Polezhaev,Oxides with Impurity Disordering: Composition, Structure, Phase Transformations [in Russian], Nauka, Moscow (1983).
V. M. Orera, R. J. Merino, and F. Pena, “Ce3+ ⇔ Ce4+ conversion in Ce-doped zirconia single crystals induced by oxide reduction treatment,”Solid State Ionics,72, 231–234 (1994).
T. Takahashi, H. Iwahare, and T. Arao, “High oxide ion conduction in sintering oxides of the system Bi2O3-Y2O3,”J. Appl. Electrochem., No. 5, 187–195 (1975).
V. V. Bakhterev and V. I. Solomonov, “A study of pulsed cathode luminescence of chrysotile-asbestos,”Dokl. Akad. Nauk,342(1), 89–91(1995).
V. V. Bakhterev and V. I. Solomonov, “Pulsed cathode luminescence of chrysotile-asbestos,”Neorgan. Mater.,31(4), 567–572 (1995).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Strekalovskii, V.N., Vovkotrub, é.G., Lipchak, A.I. et al. Luminescence of oxide ceramics in the Bi2O3-Er2O3-CeO2 system. Refract Ind Ceram 40, 51–55 (1999). https://doi.org/10.1007/BF02762446
Issue Date:
DOI: https://doi.org/10.1007/BF02762446