Abstract
Experimental data are presented which demonstrate that hydroxylapatite, which per se cannot be cured by water, acquires the ability to set when mixed with calcined calcium monobasic phosphate. The content and extent of condensation of the phosphoric acids forming during the calcination of Ca(H2PO4)2 are shown to have a strong effect on the nature and rates of the chemical and phase transformations involved and, accordingly, on the properties of the resulting cement. The calcination conditions are optimized to obtain materials suitable for eliminating injuries to dental and bone tissues.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Doremus, R.H., Bioceramics (Review),J. Mater. Sci., 1992, vol. 27, no. 2, pp. 285–297.
Sarkisov, P.D. and Mikhailenko, N.Yu., New Inorganic Materials for Medical Applications,Izv. Aakad. Nauk,Ser. Khim., 1997, no. 2, pp. 246–253.
Nicholson, J.W., The Chemistry of Teeth and Bones,Educ. Chem., 1994, vol. 31, no. 1, pp. 11–13.
Mal’kov, M.A., Lipochkin, S.V., Lisin, Yu.M., and Tyuleneva, L.N., Calcium Phosphate Ceramics for Medical Applications,Steklo Keram., 1991, no. 7, pp. 28–29.
Miyamoto, Y., Ishikawa, K., Fukao, H.,et al.,. In Vivo Setting Behaviour of Fast-Setting Calcium Phosphate Cement,Biomaterials, 1995, vol. 16, no. 11, pp. 855–860.
Konstant, Z.A. and Dindune, A.P.,Fosfaty dvukhvalentnykh metallov (Divalent-Metal Phosphates), Riga: Zinatne, 1987, p. 52.
Bermudez, O., Boltong, M.G., Driessens, F.C.M., and Pianeil, J.A., Optimization of a Calcium Phosphate Cement,J. Mater. Sci. Mater. Med., 1994, vol. 5, no 2, pp. 67–71.
Shchegrov, L.N.,Fosfaty dvukhvalentnykh metallov (Divalent-Met al. Phosphates), Kiev: Naukova Dumka, 1987, p. 58.
Belous, N.Kh., Samuskevich, V.V., and Ermolenko, I.N., Chemical Transformations Accompanying Setting of a Copper Phosphate Binder,Vestsi Akad. Navuk BSSR, Ser. Khim. Navuk, 1981, no. 2, pp. 9–12.
Prodan, E.A., Prodan, L.I. and Ermolenko, N.F.,Tripolifosfaty (Tripolyphosphates), Minsk: Nauka i Tekhnika, 1969, p. 168.
Heughebaert, J.C. and Montel, C., Reception de phosphate pure tricalcic,Bull. Soc. Chim. Fr., 1970, no. 8/9, pp. 2923–2924.
Strelyukhina, T.F.,Stomatologicheskie plombirovochnye materialy (Dental Filling Materials), Leningrad: Meditsina, 1969.
Kortukov, E.V., Voevodskii, V.S. and Pavlov, Yu.K.,Osnovy materialovedeniya (Fundamentals of Materials Research), Moscow: Vysshaya Shkola, 1988.
Prodan, E.A. and Samuskevich, V.V.,Stabil’nost’ i reaktsionnaya sposobnost’ fosfornykh solei (Stability and Reactivity of Phosphates), Minsk: Nauka i Tekhnika, 1994.
VanWazer, J.R.,Phosphorus and Its Compounds, New York: Interscience, 1958. Translated under the titleFosfor i ego soedineniya, Moscow: Inostrannaya Literatura, 1962.
Samuskevich, V.V. and Prodan, E.A., Stability of Anion Forms of Acid Phosphates,Zh. Prikl. Khim., 1993, vol. 66, no. 5, pp. 999–1003.
Belous, N.Kh., Samuskevich, V.V., and Stukalenko, A.A., Heat Treatment of Setting Liquids: Effect on the Composition and Properties of Phosphate Binders,Vestsi Akad. Navuk BSSR, Sen Khim. Navuk, 1997, no. 3, pp. 107–111.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Samuskevich, V.V., Belous, N.K., Samuskevich, L.N. et al. Watersetting cement based on hydroxylapatite and heattreated calcium monobasic phosphate. Inorg Mater 36, 964–968 (2000). https://doi.org/10.1007/BF02758714
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02758714