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Halogenation of metalloporphyrins

Abstract

We found that thionyl chloride can chlorinate porphyrin complexes with transient metals (Pd, Ni, or Cu) at the free β andmeso-positions of the porphyrin macrocycle. A more prolonged or rigorous treatment also causes the chlorination of side alkyl substituents, mainly, methyl groups.

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Correspondence to A. F. Mironov.

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Rumyantseva, V.D., Aksenova, E.A., Ponamoreva, O.N. et al. Halogenation of metalloporphyrins. Russ J Bioorg Chem 26, 423–428 (2000). https://doi.org/10.1007/BF02758672

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  • DOI: https://doi.org/10.1007/BF02758672

Key words

  • chlorination
  • metalloporphyrins
  • thionyl chloride
  • transient metals