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Halogenation of metalloporphyrins

Russian Journal of Bioorganic Chemistry volume 26, pages 423–428 (2000)Cite this article

Abstract

We found that thionyl chloride can chlorinate porphyrin complexes with transient metals (Pd, Ni, or Cu) at the free β andmeso-positions of the porphyrin macrocycle. A more prolonged or rigorous treatment also causes the chlorination of side alkyl substituents, mainly, methyl groups.

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Authors and Affiliations

  1. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, 117571, Moscow, Russia

    V. D. Rumyantseva, E. A. Aksenova, O. N. Ponamoreva & A. F. Mironov

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  1. V. D. Rumyantseva
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  2. E. A. Aksenova
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  3. O. N. Ponamoreva
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  4. A. F. Mironov
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Correspondence to A. F. Mironov.

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Rumyantseva, V.D., Aksenova, E.A., Ponamoreva, O.N. et al. Halogenation of metalloporphyrins. Russ J Bioorg Chem 26, 423–428 (2000). https://doi.org/10.1007/BF02758672

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  • DOI: https://doi.org/10.1007/BF02758672

Key words

  • chlorination
  • metalloporphyrins
  • thionyl chloride
  • transient metals