Abstract
Topological images of the Ge-Sb-Te phase diagram are constructed on the basis of two versions of the phase relations between the low-temperature forms of Ge1-δTe in the Ge-Te system. The images have the form of flow diagrams and graphs, with labeled nodes representing the phases existing in the system. The graph edges represent two-phase mixtures and are labeled by the numbers of the phase reactions in which these mixtures appear and disappear. The graphs help to visualize the topology of the phase diagram in a compact form and are convenient for topological characterization and identification of phase reactions at invariant points.
Similar content being viewed by others
References
Vogel, R.,Die heterogenen Gleichgewichte, Leipzig: Akademie, 1937.
Connel, R.G., A Tutorial on Flow Diagrams: A Tool for Developing the Structure of Multicomponent Phase Diagrams,J. Phase Equilib., 1994, vol. 15, no. 1, pp. 6–19.
Kosyakov, V.l., Kraeva, A.G., Fedorova, Zh.N., and Sinyakova, E.F., Topological Analysis of the Evolution of Phase Equilibria in the Fe-Ni-S System atx s ≤ 0.5 during Cooling,Geol. Geofiz., 1996, vol. 37, no. 12, pp. 7–17.
Kosyakov, V.I., Shestakov, V.A., Shelimova, L.E.,et al., Topological Characterization of the Bi-Ge-Te Phase Diagram,Neorg. Mater, 2000, vol. 36, no. 3, pp. 261–271 [Inorg. Mater. (Engl. Transi.), vol. 36, no. 3, pp. 201–210].
Glazov, V.M. and Zemskov, VS.,Fiziko-khimicheskie osnovy legirovaniya poluprovodnikov (Physicochemical Principles of Semiconductor Doping), Moscow: Nauka, 1967.
Olesinsky, R.W. and Abbaschian, G.I., The Ge-Sb (Germanium-Antimony) System,Bull. Alloy Phase Diagrams, 1986, vol. 7, no. 3, pp. 219–222.
Ghosh, G., The Sb-Te (Antimony-Tellurium) System,J. Phase Equilib., 1994, vol. 15, no. 3, pp. 343–360.
Shelimova, L.E., Karpinskii, O.G., Kretova, M.A.,et al., Homologous Series of Layered Tetradymite-like Compounds in the Sb-Te and GeTe-Sb2Te3 Systems,Neorg. Mater., 2000, vol. 36, no. 8, pp. 928–936 [Inorg. Mater. (Engl. Transi.), vol. 36, no. 8, pp. 768–775].
Stasova, M.M., Crystal Structures of Bismuth Selenides, Bismuth Tellurides, and Antimony Tellurides,Zh. Strukt. Khim., 1967, vol. 8, no. 4, pp. 655–661.
Stasova, M.M., Crystal Structures of Bismuth Selenides and Antimony and Bismuth Tellurides,Extended Abstract of Cand. Sci. (Chem.) Dissertation, Moscow: Moscow Inst. of Fine Chemical Technology, 1967.
Stasova, M.M., X-ray Diffraction Study of Bismuth and Antimony Chalcogenides,Zh. Strukt. Khim., 1964, vol. 5, no. 5, pp. 793–794.
Hansen, M. and Anderko, K.,Constitution of Binary Alloys, New York: McGraw-Hill, 1958, 2nd ed. Translated under the titleStruktury dvoinykh splavov, Moscow: Metallurgizdat, 1962, vol. 2.
Shelimova, L.E., Abrikosov, N.Kh. and Zhdanova, V.V., Phase Relations in the Ge-Te System near GeTe,Zh. Neorg. Khim., 1965, vol. 10, no. 5, pp. 1200–1205.
Abrikosov, N.Kh., Karpinskii, O.G., Shelimova, L.E., Korzhuev, M.A., Physicochemical Study of Germanium Telluride in the Region of Phase Transitions,Izv. Akad. Nauk SSSR, Neorg. Mater., 1977, vol. 13, no. 12, pp. 2160–2164.
Korzhuev, M.A., Petrov, L.A., Teplov, O.A., and Demenskii, G.K., Melting and Crystallization of Ge1-xTex,Izv. Akad. Nauk SSSR, Met., 1983, no. 1, pp. 36–38.
Legendre, B. and Souleau, C., Contribution à l’étude du diagramme d’équilibre des phases du système Ge-Te autour de GeTe1+x,C. R. Acad. Sci. C, 1977, vol. 284, no. 7, pp. 315–318.
Legendre, B. and Souleau, C., The Ternary System Gold-Germanium-Tellurium: Contribution to the Study of Binary Systems Germanium-Tellurium and Gold-Germanium,J. Chem. Res. Symp., 1977, pp. 306–307.
Abrikosov, N.Kh. and Danilova-Dobryakova, G.T., Sb2Te3-GeTe Phase Diagram,Izv. Akad. Nauk SSSR, Neorg. Mater, 1965, vol. 1, no. 2, pp. 204–209.
Karpinsky, O.G., Shelimova, L.E., Kretova, M.A., and Fleurial, J.-P., An X-ray Study of the Mixed-Layer Compounds of (GeTe)n(Sb2Te3)m Homologous Series,J. Alloys Compd., 1998, vol. 268, pp. 112–117.
Abrikosov, N.Kh. and Danilova-Dobryakova, G.T., Ternary System Ge-Sb-Te,Izv. Akad. Nauk SSSR, Neorg. Mater, 1970, vol. 6, no. 3, pp. 475–481.
Legendre, B., Hancheng, B., Bordas, S., and Clavaguera-Mora, M.T., Phase Diagram of the Ternary System Ge-Sb-Te: I. The Subternary GeTe-Sb2Te3-Te,Thermochim. Acta, 1984, vol. 78, pp. 141–157.
Bordas, S., Clavaguera-Mora, M.T., Legendre, B., and Hancheng, B., Phase Diagram of the Ternary System Ge-Sb-Te: II. The Subternary Ge-GeTe-Sb2Te3-Sb,Thermochim. Acta, 1986, vol. 107, pp. 239–265.
Lebaudy, P., Saiter, J.M., Grenet, J.,et al., Identification of Amorphous Zones in the GeTeSb System,Mater. Sci. Eng., A, 1991, vol. 132, pp. 273–276.
Nisel’son, L.A. and Yaroshevskii, A.G.,Mezhfaznye koeffitsienty raspredeleniya (Partition Coefficients), Moscow: Nauka, 1992.
Ehlers, E.,The Interpretation of Geological Phase Diagrams, San Francisco: Freeman, 1972. Translated under the titleInterpretatsiya fazovykh diagramm v geologii, Moscow: Mir, 1975.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kosyakov, V.I., Shestakov, V.A., Shelimova, L.E. et al. Topological characterization of the Ge-Sb-Te phase diagram. Inorg Mater 36, 1004–1017 (2000). https://doi.org/10.1007/BF02757976
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02757976