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Phosphorimetric determination of polynuclear aromatic hydrocarbons in gasoline

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Abstract

The possibility of determining pyrene, anthracene, and fluorene in gasoline by phosphorimetry at room temperature after the micellar extraction with sodium dodecyl sulfate was examined. It was found that the above polynuclear aromatic hydrocarbons simultaneously present in gasoline can be selectively determined by room-temperature phosphorimetry using different techniques for the excitation and population of the triplet states of luminophore (stationary and pulse excitation and triplet energy transfer). The proposed procedure was verified by gas chromatography with a mass-selective detector.

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References

  1. Alekseeva, T.A. and Teplitskaya, T.A.,Spektrofluorimetricheskie metody analiza aromaticheskikh uglevodorodov v prirodnykh i tekhnogennykh sredakh (Spectrophotometric Methods of Analysis of Aromatic Hydrocarbons in Natural and Technogenic Samples), Leningrad: Gidrometeoizdat, 1981.

    Google Scholar 

  2. Maistrenko, V.N., Khamitov, R.Z., and Budnikov, G.K.,Ekologo-analiticheskii monitoring supertoksikantov (Ecological Analytical Monitoring of Superecotoxicants), Moscow: Khimiya, 1996.

    Google Scholar 

  3. Shpol’skii, E.V.,Zh. Prikl. Spektrosk., 1967, vol. 7, no. 4, p. 492.

    CAS  Google Scholar 

  4. Levshin, L.V., Shtykov, S.N., Goryacheva, Yu.I., and Mel’nikov, G.V.,Zh. Prikl. Spektrosk., 1999, vol. 66, no. 2, p. 201.

    Google Scholar 

  5. Goryacheva, I.Yu., Rusanova, T.Yu., Shtykova, L.S.,et al., Khimiya: Sostoyanie i perspektivy nauchnykh issledovanii na poroge tret’ego tysyacheletiya: Sbornik statei molodykh uchenykh (Chemistry: Current State and Prospects for Scientific Research at the Threshold of the Third Millenary: Collection of Articles of Junior Researchers), Saratov: Saratov Gos. Univ., 1999, p. 29.

    Google Scholar 

  6. Mel’nikov, G.V., Goryacheva, I.Yu., and Shtykov, S.N.,Dokl. Akad. Nauk, 1998, vol. 361, no. 1, p. 72.

    Google Scholar 

  7. Shtykov, S., Melnikov, G., and Goryacheva, I.,J. Mol. Struct., 1999, vol. 482/483, p. 697.

    Article  Google Scholar 

  8. Pramauro, E. and Prevot, A.B.,Pure Appl. Chem., 1995, vol. 67, no. 4, p. 551.

    Article  CAS  Google Scholar 

  9. Savvin, S.B., Chernova, R.K., and Shtykov, S.N.,Poverkhnostno-aktivnye veshchestva (Surfactants), Moscow: Nauka, 1991.

    Google Scholar 

  10. Mackay, D. and Shiu, W.Y.,J. Chem. Eng. Data, 1977, vol. 22, no. 4, p. 399.

    Article  CAS  Google Scholar 

  11. Almgren, M., Grieser, F., and Thomas, J.K.,J. Am. Chem. Soc., 1979, vol. 101, no. 2, p. 279.

    Article  CAS  Google Scholar 

  12. Doerffel, K.,Statistik in der analytischen Chemie,Leipzig: Grundstoffindustrie, 1990, 5th ed. Translated under the titleStatistika v analiticheskoi khimii, Moscow: Mir, 1994.

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Authors and Affiliations

  1. Chemyshevsky State University, ul. Astrakhanskaya 83, 410026, Saratov, Russia

    I. Yu. Goryacheva & S. N. Shtykov

  2. Saratov State Technical University, ul. Politekhnicheskaya 77, 510054, Saratov, Russia

    G. V. Mel’nikov

  3. Saratov Military Institute of Radiation, Chemical, and Biological Defense, pr. 50-letiya Oktyabrya 5, 410037, Saratov, Russia

    A. S. Ponomarev

Authors
  1. I. Yu. Goryacheva
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  2. G. V. Mel’nikov
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  3. S. N. Shtykov
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  4. A. S. Ponomarev
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Goryacheva, I.Y., Mel’nikov, G.V., Shtykov, S.N. et al. Phosphorimetric determination of polynuclear aromatic hydrocarbons in gasoline. J Anal Chem 55, 795–798 (2000). https://doi.org/10.1007/BF02757918

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  • DOI: https://doi.org/10.1007/BF02757918

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