Skip to main content
SpringerLink
Log in

Maleic anhydride as a reagent for the determination of hydroxyl groups in organic compounds

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

The reaction of esterification by maleic anhydride in methyl ethyl ketone in the presence of triethylamine is proposed for the determination of alcohol hydroxyl groups. The equivalent amount of maleic anhydride that entered into the reaction is determined spectrophotometrically by the reaction with 2-methylimidazole. In the determination of hydroxyl groups in epoxy-dian resins, maleic anhydride is determined by the potentiometric titration with alkali after hydrolysis with water by the first potential jump.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Siggia, S. and Hanna, J.G.,Quantitative Organic Analysis via Functional Groups, New York: Wiley, 4 ed., 1980. Translated under the titleKolichestvennyi organicheskii analiz po funktsional’nym gruppam, Moscow: Khimiya, 1983, vol. 1.

    Google Scholar 

  2. Siggia, S.,Instrumental Methods of Organic Functional Group Analysis, New York: Willey-Interscience, 1972.

    Google Scholar 

  3. Kalinina, L.S., Motorina, M.A., Nikitina, N.I., and Khachapuridze, N.A.,Analiz kondensatsionnykh polimerov (Analysis of Condensed Polymers), Moscow: Khimiya, 1984.

    Google Scholar 

  4. Kreshkov, A.P., Bykova, L.N., and Kazaryan, N.A.,Kislotno-osnovnoe titrovanie v nevodnykh rastvorakh (Acid-Base Titration in Nonaqueous Solutions), Moscow: Khimiya, 1967.

    Google Scholar 

  5. Kluger, R. and Hunt, J.,J. Am. Chem. Soc., 1989, vol. 111, p. 3325.

    Article  CAS  Google Scholar 

  6. Kluger, R. and Hunt, J.,J. Am. Chem. Soc., 1984, vol. 106, p. 5667.

    Article  CAS  Google Scholar 

  7. Zaitsev, B.E. and Matyushenko, V.V.,Koord. Soedin., 1996, vol. 41, p. 1675.

    CAS  Google Scholar 

  8. Evtushenko, Yu.M., Zaitsev, B.E., Ivanov, V.M.,et al., Zh. Anal. Khim., 2000, vol. 55, no. 2, p. 161.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. AOZT Elektroizolit, Khot’kovo, Sergiev-Posad raion, 141350, Moscow oblast, Russia

    Yu. M. Evtushenko

  2. Peoples’ Friendship University, ul. Ordzhonikidze 3, 119517, Moscow, Russia

    B. E. Zaitsev

  3. Department of Chemistry, Moscow State University, Vorob’evy gory, 119899, Moscow, Russia

    V. M. Ivanov

Authors
  1. Yu. M. Evtushenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. E. Zaitsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Evtushenko, Y.M., Zaitsev, B.E. & Ivanov, V.M. Maleic anhydride as a reagent for the determination of hydroxyl groups in organic compounds. J Anal Chem 55, 859–862 (2000). https://doi.org/10.1007/BF02757850

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02757850

Keywords

Search

Navigation