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Association of the metal accumulation in a high-voltage electrodeposition with the supporting-acid dissociation constant

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Abstract

The dependence of the limiting discharge current of cations on their concentrationc 1 in a high-voltage mode is simulated numerically on a computer. The experimentally observed direct relationship between the exaltation current andc 1 occurs when the equilibrium concentration of hydrogen ions formed in the supporting-acid dissociation is higher thanc 1. With increasing acid dissociation, the current exaltation decreases, and the range of the metal ion concentrations where the dependence of the exaltation current onc 1 is linear extends.

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Authors and Affiliations

  1. Institute of SolidState Chemistry and Mechanical Chemistry, Siberian Division, Russian Academy of Sciences, ul. Kutateladze 18, 630128, Novosibirsk, Russia

    R. Yu. Bek, L. I. Shuraeva, V. N. Kiryushov & L. I. Skvortsova

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  1. R. Yu. Bek
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  2. L. I. Shuraeva
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  3. V. N. Kiryushov
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  4. L. I. Skvortsova
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Bek, R.Y., Shuraeva, L.I., Kiryushov, V.N. et al. Association of the metal accumulation in a high-voltage electrodeposition with the supporting-acid dissociation constant. Russ J Electrochem 36, 68–70 (2000). https://doi.org/10.1007/BF02757799

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  • DOI: https://doi.org/10.1007/BF02757799

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