Skip to main content
SpringerLink
Log in

Two-stage mechanism of the dicarbollyliron redox-reaction at electrode coated with a monolayer of behenic acid and hemin

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The dicarbollyliron (Cb2Fe-) redox reaction is studied at an amalgamated platinum electrode coated with a monolayer of behenic acid on top of which hemin is adsorbed. The redox reaction of Cb2Fe- involves two stages. First, an electrochemical reaction of adsorbed hemin proceeds, which involves the electron transfer through the dielectric monolayer; it is followed by the hemin’s chemical redox reaction with dissolved Cb2Fe-. It is shown that the adsorbed hemin transformation, no matter how small, is sufficient for the stimulation of the Cb2Fe- redox reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Khanova, L.A. and Krishtalik, L.I.,Elektrokhimiya, 1998, vol. 34, p. 5.

    Google Scholar 

  2. Khanova, L.A.,Elektrokhimiya, 1999, vol. 35, p. 618.

    Google Scholar 

  3. Khanova, L.A. and Tarasevich, M.R.,Elektrokhimiya, 1995, vol. 31, p. 212.

    Google Scholar 

  4. Ksenzhek, O.S. and Petrova, S.A.,Bioelectrochem. Bioenerg., 1978, vol. 5, p. 661.

    Article  CAS  Google Scholar 

  5. Bagotzky, V.S. and Yablokova, I.E.,Th. Fiz, Khim., 1953, vol. 27, p. 1663.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 117071, Moscow, Russia

    L. A. Khanova

Authors
  1. L. A. Khanova
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khanova, L.A. Two-stage mechanism of the dicarbollyliron redox-reaction at electrode coated with a monolayer of behenic acid and hemin. Russ J Electrochem 36, 54–59 (2000). https://doi.org/10.1007/BF02757796

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02757796

Keywords

Search

Navigation