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Reversibility of the lithium—vanadium bronze structure when cycled

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Abstract

Positive electrodes of secondary lithium batteries, based on Li1 + xV3O8 obtained by the alcoxytechnology, are studied. As lithium intercalates, the initial crystalline bronze turns amorphous, remaining single-phase. An increase in the lithiation degreex leads to an almost linear decrease in parametera and increase in parametersb andc of the bronze crystal lattice; the changes are quite reversible when cycling. A noticeable degradation of electric characteristics of electrodes is unrelated to irreversible structural changes and may be explained by the formation of passive films on the bronze surface.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiipr. 59, 117333, Moscow, Russia

    S. V. Pushko, O. Yu. Grigor’eva, A. K. Ivanov-Shitz & A. M. Skundin

  2. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskiipr. 31, 117071, Moscow, Russia

    O. Yu. Grigor’eva & A. M. Skundin

Authors
  1. S. V. Pushko
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  2. O. Yu. Grigor’eva
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  3. A. K. Ivanov-Shitz
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  4. A. M. Skundin
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Pushko, S.V., Grigor’eva, O.Y., Ivanov-Shitz, A.K. et al. Reversibility of the lithium—vanadium bronze structure when cycled. Russ J Electrochem 36, 802–805 (2000). https://doi.org/10.1007/BF02757686

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  • DOI: https://doi.org/10.1007/BF02757686

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