Skip to main content
SpringerLink
Log in

Co-cation conduction of the (Na1-x K x )3.8M0.1P2O7 (M = Ca, Sr, Cd) solid solutions

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Samples of systems (Na 1-x K x )3.8M0.1P2O7 (M = Ca, Sr, Cd; 0 ≤x ≤ 1) are synthesized. It is established that solid solutions with the structure of γ-K4P2O7 form in these systems. At room temperature, the solutions exist atx ≥ 0.7. In the calcium-containing system, they form a continuous series at temperatures exceeding ∼500°C. The co-cation character of conduction of the solutions is confirmed by measured transport numbers. The concentration dependences of the electroconductivity and its activation energy point to a polyalkali effect, which decreases with an increase in the M2+ ion radius. Partial conductivities of sodium and potassium cations in the (Na 1-x K x )3.8Ca0.1P2O7 system are calculated and their dependences on the balance between alkali cations in the solid solution are discussed

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Shekhtman, G.Sh., Smirnov, N.B., and Burmakin, E.I.,Elektrokhimiya, 2000, vol. 36, p. 493.

    Google Scholar 

  2. Burmakin, E.I. and Shekhtman, G.Sh.,Elektrokhimiya, 1998, vol. 34, p. 497.

    Google Scholar 

  3. Shekhtman, G.Sh., Burmakin, E.I., and Korovenkova, E.S.,Elektrokhimiya, 1999, vol. 35, p. 223.

    Google Scholar 

  4. Shekhtman, G.Sh., Smirnov, N.B., and Burmakin, E.I.,Elektrokhimiya, 2000, vol. 36, p. 490.

    Google Scholar 

  5. Smirnov, N.B., Burmakin, E.I., and Shekhtman, G.Sh.,Elektrokhimiya, 1996, vol. 32, p. 539.

    Google Scholar 

  6. Bergman, A.G. and Goryacheva, V.P.,Zh. Neorg. Khim., 1962, vol. 7, p. 2444.

    CAS  Google Scholar 

  7. Morey, G.W., Boyd, F.R., England, J.L., and Chen, W.T.,J. Am. Chem. Soc, 1955, vol. 77, p. 5003.

    Article  CAS  Google Scholar 

  8. Smirnov, N.B., Burmakin, E.I., and Shekhtman, G.Sh.,Elektrokhimiya, 1996, vol. 32, p. 1393.

    Google Scholar 

  9. Isard, J.O.,J. Non-Cryst. Solids, 1969, vol. 1, p. 235.

    Article  CAS  Google Scholar 

  10. Ishii, T. and Ishikawa, T.,Solid State Ionics, 1990, vol. 40/41, p. 227.

    Article  Google Scholar 

  11. Ito, S., Nariki, S., Kozawa, K.,et al, Solid State Ionics, 1994, vol. 72, p. 300.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 20, 620219, Yekaterinburg, Russia

    N. B. Smirnov, E. I. Burmakin, B. D. Antonov & G. Sh. Shekhtman

Authors
  1. N. B. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. I. Burmakin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. D. Antonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. Sh. Shekhtman
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Smirnov, N.B., Burmakin, E.I., Antonov, B.D. et al. Co-cation conduction of the (Na1-x K x )3.8M0.1P2O7 (M = Ca, Sr, Cd) solid solutions. Russ J Electrochem 36, 736–740 (2000). https://doi.org/10.1007/BF02757673

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02757673

Keywords

Search

Navigation