Abstract
Quantum-chemical calculations predicted that the diequatorial and diaxial conformations oftrans-isomers of methylcyclohexene acids and their esters are equally favorable. The characteristic features of the gas-chromatographic retention oftrans-2-methylcyclohexene-3-carboxilic acid can be explained by the pre-dominance of the diaxial conformation of this isomer under the conditions of the Chromatographic experiment
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Rudenko, B.A., Maslov, I.V. Characteristic features of the gas-chromatographic retention of isomeric methylcyclohexene acids and their esters. J Anal Chem 55, 37–39 (2000). https://doi.org/10.1007/BF02757630
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DOI: https://doi.org/10.1007/BF02757630