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Effect of surfactant mixtures on electrochemical processes: An estimation by the principle of linearity of free energies

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Abstract

The free-energy linearity principle can be used for interpreting the effect a mixture of surfactants of a common reaction series has on the metal corrosion, passivation, and electrodeposition currents. This follows from the current measurements in the presence of 2–6 component mixtures ofo-oxyazomethin derivatives with allowance for a mole fraction of each component.

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References

  1. Kolotyrkin, Ya.M.,Metall i korroziya (Corrosion of Metals), Moscow: Metallurgiya, 1985.

    Google Scholar 

  2. Kolotyrkin, Ya.M.,Zashch. Met., 1993, vol. 29, p. 179.

    Google Scholar 

  3. Hammett, L.,Physical Organic Chemistry: Reaction Rates, Equilibrium and Mechanisms, New York: McGraw-Hill, 1970.

    Google Scholar 

  4. Zhdanov, Yu.A. and Minkin, V.I.,Korrelyatsionnyi analiz v organicheskoi khimii (The Correlation Analysis in Organic Chemistry), Rostov-on-Don: Rostov. Univ., 1965.

    Google Scholar 

  5. Grigor’ev, V.P. and Ekilik, V.V.,Khimicheskaya struktura i zashchitnoe deistvie ingibitorov korrozii (Chemical Structures and Protective Effects of Corrosion Inhibitors), Rostov-on-Don: Rostov. Univ., 1978.

    Google Scholar 

  6. Ekilik, V.V. and Grigor’ev, V.P.,Priroda rastvoritelya i zashchitnoe deistvie ingibitorov korrozii (Solvent Nature and Protective Action of Corrosion Inhibitors), Rostovon-Don: Rostov. Univ., 1984.

    Google Scholar 

  7. Kuznetsov, Yu.I.,Organic Inhibitors of Corrosion of Metals, New York: Plenum, 1996, p. 280.

    Google Scholar 

  8. Grigor’ev, V.P., Shpan’ko, S.P. and Narezhnaya, E.V.,Zashch. Met., 1994, vol. 30, p. 260.

    CAS  Google Scholar 

  9. Grigor’ev, V.P., Shpan’ko, S.P. and Narezhnaya, E.V.,Zashch. Met., 1994, vol. 30, p. 542.

    CAS  Google Scholar 

  10. Grigor’ev, V.P., Skvortsov, E.A. and Rudnev, M.I.,Zashch. Met., 1995, vol. 31, p. 285.

    Google Scholar 

  11. Grigor’ev, V.P., Shpan’ko, S.P. and Dymnikova, O.V.,Zashch. Met., 1999, vol. 35, p. 610.

    Google Scholar 

  12. Granovskii, A.D., Sadimenko, A.P., Osipov, O.A. and Tsintsadze, G.V.,Zhestko-myagkoe vzaimodeistvie v koordinatsionnoi khimii (Hard-Soft Interaction in the Coordination Chemistry), Rostov-on-Don: Rostov. Univ., 1986.

    Google Scholar 

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Authors and Affiliations

  1. Rostov State University, pr. Stachki 194, 344104, Rostovon-Don, Russia

    V. P. Grigor’ev, S. P. Shpan’ko, A. F. Nassar & O. V. Dymnikova

Authors
  1. V. P. Grigor’ev
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  2. S. P. Shpan’ko
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  3. A. F. Nassar
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  4. O. V. Dymnikova
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Dedicated to the ninetieth anniversary of Ya.M. Kolotyrkin’s birth.

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Grigor’ev, V.P., Shpan’ko, S.P., Nassar, A.F. et al. Effect of surfactant mixtures on electrochemical processes: An estimation by the principle of linearity of free energies. Russ J Electrochem 36, 1157–1162 (2000). https://doi.org/10.1007/BF02757538

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  • DOI: https://doi.org/10.1007/BF02757538

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