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Dissolution kinetics of hydrophilic metal at medium coverages of its surface by specifically adsorbed anions

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Abstract

The iron dissolution rate, determined earlier by a statistical calculation for low coverages of the surface by specifically adsorbed anions Aads and oxygen atoms Oads under the assumption that the dissolution and passivation processes are separated in space, is shown to be applicable for any coverages by Aads. The calculation agrees with experiment if the short lifetime of Aads (as compared with that of Oads) is taken into account.

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Authors and Affiliations

  1. Russian Federation Scientific Center “Karpov Research Institute of Physical Chemistry” (Obninsk Branch), Obninsk, 249020, Kaluga oblast, Russia

    R. M. Lazorenko-Manevich & L. A. Sokolova

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  1. R. M. Lazorenko-Manevich
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  2. L. A. Sokolova
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Dedicated to the ninetieth anniversary of Ya.M. Kolotyrkin’s birth.

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Lazorenko-Manevich, R.M., Sokolova, L.A. Dissolution kinetics of hydrophilic metal at medium coverages of its surface by specifically adsorbed anions. Russ J Electrochem 36, 1149–1156 (2000). https://doi.org/10.1007/BF02757537

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  • DOI: https://doi.org/10.1007/BF02757537

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