Journal of Analytical Chemistry

, Volume 55, Issue 5, pp 445–448 | Cite as

Determination of hydrazides and 1,2-diacylhydrazines of aliphatic carboxylic acids by conductometric titration

  • A. V. Radushev
  • L. G. Chekanova
  • V. Yu. Gusev
  • E. A. Sazonova


A procedure is developed for the conductometric titration of hydrazides and 1,2-diacylhydrazines of aliphatic carboxylic acids with HCl or KOH in nonaqueous and water-alcohol solutions. The procedure is suitable for the determination of the major substance in hydrazides of C5H11-C12H25 aliphatic carboxylic acids and CH3-C7H15 1,2-diacylhydrazines and for the analysis of reaction mixtures containing N2H4, RCOOH, and RCOOH · N2H4 along with the major substance.


Carboxylic Acid Hydrazine Hydrazide Hydrazine Hydrate Acid Hydrazide 
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  1. 1.
    Ioffe, B.V., Kuznetsov, M.A., and Potekhin, A.A.,Khimiya organicheskikh proizvodnykh gidrazina (Chemistry of Organic Hydrazine Derivatives), Leningrad: Khimiya, 1979.Google Scholar
  2. 2.
    Radushev, A.V., Gusev, V.Yu., Bogomazova, G.S.,et al., Zh. Prikl. Khim. (Leningrad), 1996, vol. 69, no. 8, p. 1283.Google Scholar
  3. 3.
    Teterina, N.N., Radushev, A.V., Adeev, S.M.,et al., Zh. Prikl. Khim. (Leningrad), 1995, vol. 68, no. 1, p. 3.Google Scholar
  4. 4.
    Grekov, A.P. and Marakhova, M.S.,Zh. Anal. Khim., 1961, vol. 16, no. 5, p. 643.Google Scholar
  5. 5.
    Radushev, A.V., Reshetnikova, L.G., Gusev, V.Yu.,et al., Fiziko-khimicheskie svoistva kompozitov i organicheskikh reagentov s aktivnymi funktsional’nymi gruppami (Physicochemical Properties of Composites and Organic Reagents Containing Reactive Functional Groups), Sverdlovsk: Ural. Otd. Ross. Akad. Nauk, 1991, p. 62.Google Scholar
  6. 6.
    Drozdetskii, A.G., Radushev, A.V., Turbin, A.S.,et al., Zh. Prikl. Khim. (Leningrad), 1998, vol. 71, no. 2, p. 288.Google Scholar
  7. 7.
    Radushev, A.V., Lesnov, A.E., Tarasova, N.B.,et al., Zh. Anal. Khim., 1994, vol. 49, no. 3, p. 322.Google Scholar
  8. 8.
    Siggia, S. and Hanna, J.G.,Quantitative Organic Analysis via Functional Groups, New York: Wiley, 4 ed., 1980. Translated under the titleKolichestvennyi organicheskii analizpo funktsional’nym gruppam, Moscow: Khimiya, 1983, p. 511.Google Scholar
  9. 9.
    Gusev, V.Yu., Radushev, A.V., Chernova, G.V.,et al., Zh. Obshch. Khim., 1998, vol. 68, no. 10, p. 1674.Google Scholar
  10. 10.
    Grekov, A.P.,Organicheskaya khimiya gidrazina (Organic Chemistry of Hydrazine), Kiev: Tekhnika, 1966.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2000

Authors and Affiliations

  • A. V. Radushev
    • 1
  • L. G. Chekanova
    • 1
  • V. Yu. Gusev
    • 1
  • E. A. Sazonova
    • 1
  1. 1.Institute of Technical Chemistry, Ural DivisionRussian Academy of SciencesPermRussia

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