Skip to main content
Log in

A mechanism of anomalous dust settling in a catalyst bed

  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

Anomalous dust settling by a working catalyst bed is considered. The proposed mechanism of dust settling is based on electrical phenomena near the catalyst surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Abbreviations

A 0 :

empirical coefficient in formula (3), A/(m2 K2)

C :

mean square speed of ions, m/s

D :

coefficient in formula (3) that accounts for the difference between the ideal and actual emission conditions

d :

diameter of a dust particle, m

e :

1.6 x 10-19-electron charge, C

E :

electric field strength, V/m

f t :

thermal conductivity of a particles and the gas medium (depends on particle size)

F c :

Coulomb attracting force, N

F t :

thermophoretic force, N

j :

thermionic current, A/m2

k :

Boltzmann constant

l :

radius of a catalyst grain, m

m :

ion weight, kg

N 0 :

mean ion concentration, nr-3

q :

charge of a dust particle, C

r :

radius of a dust particle, m

t :

charging time, s

T- :

absolute temperature of the gas, K

T 1 :

temperature of the gas flow, K

T 2 :

temperature of the catalyst surface, K

V :

steady-state speed of a particle, m/s

ε0 :

8.85 x 10

-12 :

permittivity of vacuum, F/m

ε:

relative permittivity (for gases, ε ≏1)

λ:

free path length of gas molecules, m

υ:

dynamic viscosity of the gas, Pa s

v:

kinematic viscosity of the gas, m2/s

Ο:

surface-charge density, C/m2

Φ:

electron work function, eV

References

  1. Amelin, A.G. and Kabanov, A.N., Aerosol Sedimentation in a Catalyst Bed,Kolloidn. Zh., 1976, vol. 38, no. 5, p. 955.

    CAS  Google Scholar 

  2. Kabanov, A.N., Weighed Particle Sedimentation in a Catalyst Bed,Cand. Sei. (Eng.) Dissertation, Moscow: Res. Inst. Fertilizers Insecticides, 1973.

    Google Scholar 

  3. Yankovska, E., Dust Collection in a Bed during a Catalytic Reaction,Cand. Sci. (Eng.) Dissertation, Moscow: Moscow Inst. Fine Chem. Technol., 1987.

    Google Scholar 

  4. Tomishko, M.M., Maslennikov, B.M., Amelin, A.G., and Kabanov, A.N., Catalytic Dust Collection,Promyshlennost’ mineral’nykh udobrenii i sernoi kisloty (The Industry of Mineral Fertilizers and Sulfuric Acid), Moscow: NIITEKhIM, 1979, no. 6, p. 12.

  5. Tomishko, M.M. and Maslennikov, B.M., The Occurrence of Potential Difference in a Vanadium Catalyst Bed during Oxidation of SO2 into SO3,Promyshlennost’ mineral’nykh udobrenii i sernoi kisloty (The Industry of Mineral Fertilizers and Sulfuric Acid), Moscow: NIITEKhIM, 1979, no. 2, p. 14.

  6. Tomishko, M.M., Nosov, V.N., Timoshenko, V.I.,et al., Charge on the Surface of an Activated Catalyst,Kinet. Katal, 1987, vol. 28, no. 1, p. 255.

    CAS  Google Scholar 

  7. Tomishko, M.M., Nevskii, I.A., Beskov, VS.,et al., Charge on the Catalyst Surface during Sulfur Dioxide Oxidation,Dokl. Akad. Nauk SSSR, 1988, vol. 302, no. 5, p. 1154.

    CAS  Google Scholar 

  8. Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V., A Plasma in the Zone of Catalytic Oxidation,Dokl. Ross. Akad. Nauk, 1995, vol. 341, no. 1, p. 75.

    CAS  Google Scholar 

  9. Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V, Charge State on the Surface of an Activated Catalyst,Khim. Prom-st., 1996, no. 12, p. 791.

  10. Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V, A Bulk Uncompensated Catalyst Charge during Catalytic Oxidation of Sulfur Dioxide,Khim. Prom-st., 1997, no. 1, p. 19.

  11. Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V, The Study of a Bulk Uncompensated Catalyst Charge during Oxidation of Sulfur Dioxide with a Faraday Chamber Placed Inside a Catalytic Reactor,Khim. Prom-st., 1997, no. 2, p. 109.

  12. Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V, Electrophysical Properties of a Gas Phase in the Zone of Catalytic Oxidation of Sulfur Dioxide,Teor. Osn. Khim. Tekhnol., 1997, vol. 31, no. 5, p. 549.

    Google Scholar 

  13. Reist, P.,Introduction to Aerosol Science, New York: Macmillan, 1984. Translated under the titleAerozoli. Vvedenie vteoriyu, Moscow: Mir, 1987.

    Google Scholar 

  14. Loeb, L.B,Static Electrification, Berlin: Springer, 1958. Translated under the titleStaticheskaya elektrizatsiya, Moscow: Gosenergoizdat, 1963.

    Google Scholar 

  15. Green, H. and Lane, W.,Particulate Clouds: Dust, Smokes, and Mists, London, 1964. Translated under the titleAerozoli-pyli, dymy, tumany, Leningrad: Khimiya, 1972.

  16. Raizer, Yu.P.,Teoriya gazovogo razryada (The Theory of Gas Discharge), Moscow: Nauka, 1987.

    Google Scholar 

  17. Myazdrikov, O.V,Elektrodinamicheskoe psevdoozhizhenie dispersnykh sistem (Electrodynamic Fluidization of Disperse Systems), Leningrad: Khimiya, 1984.

    Google Scholar 

  18. Perevalov, Yu.D., Sulfur Dioxide Oxidation in a Dusty Gas Mixture in Channels with Catalytically Active Walls,Cand. Sci. (Eng.) Dissertation, Moscow: Moscow Inst. Fine Chem. Technol., 1983.

    Google Scholar 

  19. Poddoskin, A.V, Yushkanov, A.A., and Yalamov, Yu.L, The Theory of Thermophoresis of Moderately Large Particulates,Zh. Tekh. Fiz. 1982, vol. 52, no. 11, p. 2253.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nevskii, I.A., Tomishko, M.M., Beskov, V.S. et al. A mechanism of anomalous dust settling in a catalyst bed. Theor Found Chem Eng 34, 90–93 (2000). https://doi.org/10.1007/BF02757471

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02757471

Keywords

Navigation