Abstract
Anomalous dust settling by a working catalyst bed is considered. The proposed mechanism of dust settling is based on electrical phenomena near the catalyst surface.
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Abbreviations
- A 0 :
-
empirical coefficient in formula (3), A/(m2 K2)
- C :
-
mean square speed of ions, m/s
- D :
-
coefficient in formula (3) that accounts for the difference between the ideal and actual emission conditions
- d :
-
diameter of a dust particle, m
- e :
-
1.6 x 10-19-electron charge, C
- E :
-
electric field strength, V/m
- f t :
-
thermal conductivity of a particles and the gas medium (depends on particle size)
- F c :
-
Coulomb attracting force, N
- F t :
-
thermophoretic force, N
- j :
-
thermionic current, A/m2
- k :
-
Boltzmann constant
- l :
-
radius of a catalyst grain, m
- m :
-
ion weight, kg
- N 0 :
-
mean ion concentration, nr-3
- q :
-
charge of a dust particle, C
- r :
-
radius of a dust particle, m
- t :
-
charging time, s
- T- :
-
absolute temperature of the gas, K
- T 1 :
-
temperature of the gas flow, K
- T 2 :
-
temperature of the catalyst surface, K
- V :
-
steady-state speed of a particle, m/s
- ε0 :
-
8.85 x 10
- -12 :
-
permittivity of vacuum, F/m
- ε:
-
relative permittivity (for gases, ε ≏1)
- λ:
-
free path length of gas molecules, m
- υ:
-
dynamic viscosity of the gas, Pa s
- v:
-
kinematic viscosity of the gas, m2/s
- Ο:
-
surface-charge density, C/m2
- Φ:
-
electron work function, eV
References
Amelin, A.G. and Kabanov, A.N., Aerosol Sedimentation in a Catalyst Bed,Kolloidn. Zh., 1976, vol. 38, no. 5, p. 955.
Kabanov, A.N., Weighed Particle Sedimentation in a Catalyst Bed,Cand. Sei. (Eng.) Dissertation, Moscow: Res. Inst. Fertilizers Insecticides, 1973.
Yankovska, E., Dust Collection in a Bed during a Catalytic Reaction,Cand. Sci. (Eng.) Dissertation, Moscow: Moscow Inst. Fine Chem. Technol., 1987.
Tomishko, M.M., Maslennikov, B.M., Amelin, A.G., and Kabanov, A.N., Catalytic Dust Collection,Promyshlennost’ mineral’nykh udobrenii i sernoi kisloty (The Industry of Mineral Fertilizers and Sulfuric Acid), Moscow: NIITEKhIM, 1979, no. 6, p. 12.
Tomishko, M.M. and Maslennikov, B.M., The Occurrence of Potential Difference in a Vanadium Catalyst Bed during Oxidation of SO2 into SO3,Promyshlennost’ mineral’nykh udobrenii i sernoi kisloty (The Industry of Mineral Fertilizers and Sulfuric Acid), Moscow: NIITEKhIM, 1979, no. 2, p. 14.
Tomishko, M.M., Nosov, V.N., Timoshenko, V.I.,et al., Charge on the Surface of an Activated Catalyst,Kinet. Katal, 1987, vol. 28, no. 1, p. 255.
Tomishko, M.M., Nevskii, I.A., Beskov, VS.,et al., Charge on the Catalyst Surface during Sulfur Dioxide Oxidation,Dokl. Akad. Nauk SSSR, 1988, vol. 302, no. 5, p. 1154.
Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V., A Plasma in the Zone of Catalytic Oxidation,Dokl. Ross. Akad. Nauk, 1995, vol. 341, no. 1, p. 75.
Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V, Charge State on the Surface of an Activated Catalyst,Khim. Prom-st., 1996, no. 12, p. 791.
Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V, A Bulk Uncompensated Catalyst Charge during Catalytic Oxidation of Sulfur Dioxide,Khim. Prom-st., 1997, no. 1, p. 19.
Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V, The Study of a Bulk Uncompensated Catalyst Charge during Oxidation of Sulfur Dioxide with a Faraday Chamber Placed Inside a Catalytic Reactor,Khim. Prom-st., 1997, no. 2, p. 109.
Tomishko, M.M., Nevskii, I.A., Beskov, VS., and Putilov, A.V, Electrophysical Properties of a Gas Phase in the Zone of Catalytic Oxidation of Sulfur Dioxide,Teor. Osn. Khim. Tekhnol., 1997, vol. 31, no. 5, p. 549.
Reist, P.,Introduction to Aerosol Science, New York: Macmillan, 1984. Translated under the titleAerozoli. Vvedenie vteoriyu, Moscow: Mir, 1987.
Loeb, L.B,Static Electrification, Berlin: Springer, 1958. Translated under the titleStaticheskaya elektrizatsiya, Moscow: Gosenergoizdat, 1963.
Green, H. and Lane, W.,Particulate Clouds: Dust, Smokes, and Mists, London, 1964. Translated under the titleAerozoli-pyli, dymy, tumany, Leningrad: Khimiya, 1972.
Raizer, Yu.P.,Teoriya gazovogo razryada (The Theory of Gas Discharge), Moscow: Nauka, 1987.
Myazdrikov, O.V,Elektrodinamicheskoe psevdoozhizhenie dispersnykh sistem (Electrodynamic Fluidization of Disperse Systems), Leningrad: Khimiya, 1984.
Perevalov, Yu.D., Sulfur Dioxide Oxidation in a Dusty Gas Mixture in Channels with Catalytically Active Walls,Cand. Sci. (Eng.) Dissertation, Moscow: Moscow Inst. Fine Chem. Technol., 1983.
Poddoskin, A.V, Yushkanov, A.A., and Yalamov, Yu.L, The Theory of Thermophoresis of Moderately Large Particulates,Zh. Tekh. Fiz. 1982, vol. 52, no. 11, p. 2253.
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Nevskii, I.A., Tomishko, M.M., Beskov, V.S. et al. A mechanism of anomalous dust settling in a catalyst bed. Theor Found Chem Eng 34, 90–93 (2000). https://doi.org/10.1007/BF02757471
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DOI: https://doi.org/10.1007/BF02757471