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Thermolysis of the esters of substituted 3,7-triazabicydo[3.3.0]oct-3-ene-4-carboxylic acids

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Abstract

Heating to 190–200‡C of the esters of substituted 2,3,7-triazabicyclo[3.3.0]oct-3-ene-4-carboxylic acids afforded esters of 3-azabicyclo[3.1.0]hexane-6-carboxylic acids as a mixture of exo and endo isomers. The reaction carried out in chlorobenzene at 130‡C in the presence of copper stearate yielded only exo isomers.

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Authors and Affiliations

  1. St. Petersburg State University, 198904, St.Petersburg, Russia

    S. A. Molchanov, A. V. Stepakov & R. R. Kostikov

Authors
  1. S. A. Molchanov
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  2. A. V. Stepakov
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  3. R. R. Kostikov
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Additional information

The study was carried out under financial support of the Russian Ministry of Education (grant no. 97-0-9.4-118).

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Molchanov, S.A., Stepakov, A.V. & Kostikov, R.R. Thermolysis of the esters of substituted 3,7-triazabicydo[3.3.0]oct-3-ene-4-carboxylic acids. Russ J Electrochem 36, 899–903 (2000). https://doi.org/10.1007/BF02757452

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  • DOI: https://doi.org/10.1007/BF02757452

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