Skip to main content
SpringerLink
Log in

Conventional kinetic characteristics of signals in alternating-current square-wave voltammetry

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Kinetic parameters typical of alternating-current square-wave voltammetry were considered. In the absence of precise time characteristics of instruments, we proposed to use the following conventional characteristics obtained from experimental data: instrument constant (H); kinetic parameter of irreversible electrode processes (Φ); and kinetic parameter of catalytic processes (Ψ). Particular attention was given to the effect of mercury column height on the kinetic characteristics

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kaplan, B.Ya., Pats, R.G., and Salikhdzhanova, R.M.-F.,Vol’tamperometriya peremennogo toka (Alternate-Current Voltammetry), Moscow: Khimiya, 1985.

    Google Scholar 

  2. Geissler, M. and Kuhnhardt, C.,Square-Wave Polarography, Leipzig: Grundstoffindustrie, 1970.

    Google Scholar 

  3. Bond, A.M.,Polarvgraphic Methods in Analytical Chemistry, New York: Dekker, 1980.

    Google Scholar 

  4. Osipova, E.A., Prokhorova, G.V., Agasyan, P.K., and Khapilova, N.V., Abstracts of Papers,Vsesoyuznoe soveshchanie po elektrokhimicheskim metodam analiza (All-Union Conference on Electrochemical Methods of Analysis), 1985, Tomsk, ch. 1, p. 118.

  5. Toropova, V.F., Budnikov, G.K., and Medyantseva, E.P.,Polyarografiya (Polarography), Riga: Zinatne, 1978, p. 216.

    Google Scholar 

  6. Kolthoff, I.M. and Mader, P.,Anal. Chem., 1970, vol. 42, no. 11, p. 1762.

    Article  CAS  Google Scholar 

  7. Mader, P., Kolthoff, I.M., and Vesela, V.,Electrochim. Acta, 1982, vol. 27, p. 1402.

    Article  Google Scholar 

  8. Gorokhovskaya, V.I., Svatko, L.G., and Nechipurenko, R.A., Available from VINITI, 1978, Moscow, no. 800-77.

  9. Gorokhovskaya, V.I. and Bibik, O.V., Available from VINITI, 1986, Cherkassy, no. 117khp-85.

  10. Delahay, P.,New Instrumental Methods in Electrochemistry, New York, 1954. Translated under the titleNovye pribory i metody velektrokhimii, Moscow: Inostrannaya Literatura, 1957.

  11. Galus, Z.,Teoretyczne podstawy elektroanalizy chemicznej (Theoretical Foundations of Electrochemical Analysis), Warszawa: Panstowe Wydawnictwo naukowe, 1971. Translated under the titleTeoreticheskie osnovy elektrokhimicheskogo analiza, Moscow: Mir, 1974.

    Google Scholar 

  12. Lovrich, M.,Elektrokhimiya, 1991, vol. 27, no. 2, p. 186.

    Google Scholar 

  13. O’Dea, J.J., Ribe, A., and Osteryoung, J.J.,J. Electroanal. Chem., 1993, vol. 27, nos. 1–2, p. 287.

    Article  Google Scholar 

  14. O’Dea, Osteryoung, J.J.,Anal. Chem., 1993, vol. 65, no. 21, p. 3090.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Petroleum and Petroleum Chemistry, Kazan State Technological University, ul. K. Marksa 68, Kazan, 420015, Tatarstan, Russia

    V. I. Gorokhovskaya

Authors
  1. V. I. Gorokhovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gorokhovskaya, V.I. Conventional kinetic characteristics of signals in alternating-current square-wave voltammetry. J Anal Chem 55, 216–220 (2000). https://doi.org/10.1007/BF02757202

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02757202

Keywords

Search

Navigation