Abstract
Anodic oxidation of 2-nitropropane in a methanol solution of sodium iodide and hydroxide is found to produce 2,3-dimethyl-2,3-dinitrobutane with a yield of 65-70% under optimum conditions.
Similar content being viewed by others
References
Zelinskii, N.D. and Shilov, N.N.,Zh. Ros. Fiz.-khim. Obva, 1894, vol. 26, p. 608.
Seigle, L.,Ph. D. Thesis, Purdue: Purdue Univ., 1940, p. 35.
Pearson, R. and Evans, W.,Trans. Electrochem. Soc., 1943, vol. 84, p. 173.
Wawzonek, S. and Su, T.Y.,J. Electrochem. Soc., 1973, vol. 41, p. 745.
Schaefer, H.,Chem. Eng. Techn., 1969, vol. 41, p. 179.
Tomilov, A.P. and Kirilyus, I.V.,Katodnye sintezy organicheskikh preparatov (The Cathodic Synthesis of Organic Compounds), Alma-Ata: Nauka, 1982.
White, D.,J. Electrochem. Soc., 1977, vol. 124, p. 1177.
Author information
Authors and Affiliations
Additional information
Deceased.
Rights and permissions
About this article
Cite this article
Smirnov, Y.D., Tomilov, A.P. Electrochemical Synthesis of 2,3-Dimethyl-2,3-Dinitrobutane. Russ J Electrochem 36, 211–212 (2000). https://doi.org/10.1007/BF02756908
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02756908