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Mechanism of the formation of porous silicate mesophases

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Abstract

The formation of mesoporous mesophase systems prepared by precipitation of soluble forms of SiO2 at the surface of micelles of cetyltrimethylammonium cations was examined. A molecular mechanism of the formation of a silicate coating and a macroscopic mechanism of the formation of a mesophase were found and discussed. A combination of these mechanisms describes the processes proceeding during the synthesis. It can also explain the observed changes in the structure and texture characteristics of the mesophase.

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References

  1. Corma, A.,Chem. Rev., 1997, vol. 97, no. 6, p. 2373.

    Article  CAS  Google Scholar 

  2. Raman, N.K., Anderson, M.T., and Brinker, C.J.,Chem. Mater., 1996, vol. 8, p. 1682.

    Article  CAS  Google Scholar 

  3. Sayari, A.,Chem. Mater., 1996, vol. 8, p. 1840.

    Article  CAS  Google Scholar 

  4. Corma, A.,Top. Cotal., 1997, vol. 4, p. 249.

    Article  Google Scholar 

  5. Sayari, A. and Liu, P.,Microporous Mater., 1997, vol. 12, p. 149.

    Article  CAS  Google Scholar 

  6. Huang, Y.-Y., McCarthy, T.J., and Sachtier, W.M.H.,Appl. Cotal., A, 1996, vol. 148, p. 135.

    Article  CAS  Google Scholar 

  7. Antonelly, D.M. and Ying, J.Y.,Angew. Chem., Int. Ed. Engl., 1995, vol. 34, p. 2014.

    Article  Google Scholar 

  8. Antonelly, D.M. and Ying, J.Y.,Chem. Mater., 1996, vol. 8, p. 874.

    Article  Google Scholar 

  9. Antonelly, D.M. and Ying, J.Y.,Angew. Chem., Int. Ed. Engl., 1996, vol. 35, p. 426.

    Article  Google Scholar 

  10. Antonelly, D.M., Nakahira, A., and Ying, J.Y.,Inorg. Chem., 1996,vol. 35,p. 3126.

    Article  Google Scholar 

  11. Sun, T. and Ying, J.Y.,Nature, 1997, vol. 389, p. 704.

    Article  CAS  Google Scholar 

  12. Kresge, C.T., Leonowicz, M.E., Roth, W.J.,et al., Nature, 1992, vol. 359, p. 710.

    Article  CAS  Google Scholar 

  13. Beck, J.S., Vartuli, J.C., Roth, W.J.,et al., J. Am. Chem. Soc, 1992, vol. 114, p. 10834.

    Article  CAS  Google Scholar 

  14. Monnier, A., Schuth, F., Huo, Q.,et al., Science, 1993, no. 261, p. 1299.

  15. Huo, Q., Margolese, D.I., Ciesla, U.,et al., Nature, 1994, vol. 368, p. 317.

    Article  CAS  Google Scholar 

  16. Beck, J.S., Vartuli, J.C., Kennedy, G.J.,et al., Chem. Mater., 1994, vol. 6, p. 1816.

    Article  CAS  Google Scholar 

  17. Cheng, C.-F., Luan, Z., and Klinowski, J.,Langmuir, 1995, vol. 11, p. 2815.

    Article  CAS  Google Scholar 

  18. Firouzi, A., Kumar, D., Bull, L.M.,et al., Science, 1995, vol. 267, p. 1138.

    Article  CAS  Google Scholar 

  19. Kushalani, D., Kuperman, A., Ozin, G.A.,et al., Adv. Mater., 1995, vol. 7, p. 842.

    Article  Google Scholar 

  20. Inagaki, S., Sakamoto, Y., Fukushima, Y.,et al., Chem. Mater., 1996, vol. 8, p. 2089.

    Article  CAS  Google Scholar 

  21. Corma, A., Kan, Q., Navarro, M.T.,et al., Chem. Mater., 1997, vol. 9, p. 2123.

    Article  CAS  Google Scholar 

  22. Sayari, A., Liu, P., Kruk, M.,et al., Chem. Mater., 1997, vol. 9, p. 2499.

    Article  CAS  Google Scholar 

  23. Kruk, M., Jaroniec, M., Ryoo, R.,et al., Microporous Mater., 1997, vol. 12, p. 93.

    Article  CAS  Google Scholar 

  24. Lin, H.-P., Cheng, S., and Mou, C.-Y,Microporous Mater., 1997, vol. 10, p. 111.

    Article  CAS  Google Scholar 

  25. Yoegtlin, A.C., Matijasic, A., Patarin, J.,et al., Microporous Mater., 1997, vol. 10, p. 137.

    Article  Google Scholar 

  26. Karnaukhov, A.P., Fenelonov, V.B., and Gavrilov, V.Yu.,Pure Appl Chem., 1989, vol. 61, p. 1913.

    Article  CAS  Google Scholar 

  27. Fenelonov, V.B., Romannikov, V.N., and Derevyankin, A.Yu.,Micropor. Mesopor. Mater., 1999, vol. 28, p. 57.

    Article  CAS  Google Scholar 

  28. Romannikov, V.N., Fenelonov, V.B., Paukshtis, E.A.,et al., Micropor. Mesopor. Mater., 1998, vol. 21, p. 411.

    Article  CAS  Google Scholar 

  29. Gelbert, W.M. and Ben-Shaul, A.,J. Phys. Chem., 1996, vol. 100, p. 13169.

    Article  Google Scholar 

  30. Hyde, S.T.,Colloque De Physique, 1990, vol. 57, p. 7.

    Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    V. N. Romannikov, V. B. Fenelonov, A. V. Nosov, A. Yu. Derevyankin, S. V. Tsybulya & V. N. Kolomiichuk

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  1. V. N. Romannikov
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  2. V. B. Fenelonov
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  3. A. V. Nosov
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  4. A. Yu. Derevyankin
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  5. S. V. Tsybulya
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  6. V. N. Kolomiichuk
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Romannikov, V.N., Fenelonov, V.B., Nosov, A.V. et al. Mechanism of the formation of porous silicate mesophases. Kinet Catal 41, 108–115 (2000). https://doi.org/10.1007/BF02756148

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  • DOI: https://doi.org/10.1007/BF02756148

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