Skip to main content
SpringerLink
Log in

Determination of residual amounts ofO-IsobutylS-2-(N,N-Diethylamino)ethyl methylphosphonate in decontaminating solutions by gas chromatography

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

A method is proposed for the determination ofO-isobutylS-2-(N,N-diethylamino)ethyl methylphosphonate (mixed ester, ME) in spent decontaminating solutions by gas chromatography at a level of 1 x 10-5%. The interfering effect of mono- and diisobutyl methylphosphonates (matrix components formed on the destruction of ME) is eliminated by extraction and back extraction. The effect of bis(N,N-diethylaminoethyl) disulfide in the determination of ME is eliminated by changing the order of elution from a Chromatographic column. Decontaminating solutions that are used in the laboratory practice for the detoxication of hydrophilic process ME solutions are aqueous solutions of alkali hydroxide with additions of hydrogen peroxide and an emulsifier.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Stan’kov, I.N., Polyakov, V.S., Sergeeva, A.A., and Lanin, S.N.,Zh. Anal. Khim., 1999, vol. 54, no. 2, p. 219.

    Google Scholar 

  2. Kuntsevich, A.D., Shantorokha, A.V., Bukreev, S.N.,et al., Dokl. Akad. Nauk, 1996, vol. 351, no. 5, p. 649.

    Google Scholar 

  3. Stan’kov, I.N. and Lanin, S.N.,Zh. Anal. Khim., 1997, vol. 52, no. 6, p. 647.

    Google Scholar 

  4. Soniassy, R., Sandra, P., and Schlett, C.,Water Analysis: Organic Micropollutants. A Practical Guide, Hewlett Packard, 1994. Translated under the titleAnaliz vody: organicheskie mikroprimesi. Prakticheskoe rukovodstvo, St. Petersburg: Teza, 1995.

  5. Stan’kov, I.N., Beresnev, A.N., and Lanin, S.N.,Zh. Anal. Khim., 1991, vol. 46, no. 5, p. 943.

    CAS  Google Scholar 

  6. Beresnev, A.N., Kirievskaya, M.M., Stan’kov, I.N., Sakodynskii, K.I., and Petrunin, V.A.,Zh. Fiz. Khim., 1991, vol. 65, no. 3, p. 747.

    CAS  Google Scholar 

  7. Stan’kov, I.N., Beresnev, A.N., Agureev, V.T., and Lanin, S.N.,Zh. Fiz. Khim., 1992, vol. 66, no. 12, p. 3321.

    Google Scholar 

  8. Itsikson, L.B. and Isgirev, V.F.,Zh. Anal. Khim., 1979, vol. 34, 1, p. 178.

    CAS  Google Scholar 

  9. Stan’kov, I.N., Tarasov, S.N., Lysenko, V.V.,et al., Zh. Fiz. Khim., 1990, vol. 64, no. 9, p. 2467.

    CAS  Google Scholar 

  10. GOST (State Standard)27384-87, 1987.

Download references

Author information

Authors and Affiliations

  1. State Research Institute of Organic Chemistry and Technology, sh. Entuziastov 23, 111024, Moscow, Russia

    I. N. Stan’kov, A. A. Sergeeva & I. D. Derevyagina

Authors
  1. I. N. Stan’kov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Sergeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. D. Derevyagina
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stan’kov, I.N., Sergeeva, A.A. & Derevyagina, I.D. Determination of residual amounts ofO-IsobutylS-2-(N,N-Diethylamino)ethyl methylphosphonate in decontaminating solutions by gas chromatography. J Anal Chem 55, 988–990 (2000). https://doi.org/10.1007/BF02756092

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02756092

Keywords

Search

Navigation