Kinetics and Catalysis

, Volume 41, Issue 3, pp 388–393 | Cite as

Liquid-phase hydrogenation of thiophenes on palladium sulfide catalysts

  • A. A. Zirka
  • A. V. Mashkina


Palladium sulfide catalysts are active for the hydrogenation of thiophenes of different structure in hydrocarbons at 22O-30O‡C and 3.0-9.5 MPa. Thiophenes and benzothiophenes are close in reactivity. An increase in palladium sulfide concentration in the catalyst leads to an increase in the reaction rate per 1 g of the catalyst but has only a slight effect on the specific reaction rate of hydrogenation calculated per 1 g of Pd. The specific activity of palladium sulfide supported on aluminosilicate is one order of magnitude higher than that of PdS without a support and the catalysts supported on the aluminum oxide and carbon. The aluminosilicate-supported catalyst is also more selective.


Thiophene Hydrogen Sulfide Dodecane Carbon Support Benzothiophene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Karaulova, E.N.,Poluchenie i svoistva organicheskikh soedinenii sery (Synthesis and Properties of Organosulfur Compounds), Belen’kii, L.I., Ed., Moscow: Khimiya, 1998, p. 289.Google Scholar
  2. 2.
    Mashkina, A.V.,Geterogennyi kataliz v khimii organicheskikh soedinenii sery (Heterogeneous Catalysis in Organosulfur Chemistry), Novosibirsk: Nauka, 1977.Google Scholar
  3. 3.
    Mashkina, A. V.,Sulfur Rep., 1991, vol. 10, no. 4, p. 279.CrossRefGoogle Scholar
  4. 4.
    Zirka, A.A., Sagitulin, R.S., Masagutov, R.M.,et al., React. Kinet. Catal. Lett, 1984, vol. 25, nos. 1–2, p. 171.CrossRefGoogle Scholar
  5. 5.
    Zirka, A.A., Yermakova, A., and Mashkina, A.V.,React. Kinet. Catal. Lett, 1991, vol. 43, no. 2, p. 487.CrossRefGoogle Scholar
  6. 6.
    Kulishkin, N.T., Mashkina, A.V., Buyanova, N.E.,et al., Kinet. KataL, 1971, vol. 12, no. 6, p. 1539.Google Scholar
  7. 7.
    Kalinina, N.G., Poluboyarov, V.A., Anufrienko, V.F.,et al., Kinet. KataL, 1987, vol. 28, no. 5, p. 1253.Google Scholar
  8. 8.
    Obolentsev, R.D. and Baikova, A.Ya.,Seraorganicheskie soedineniya neftei Uralo-Povolzh’ya i Sibiri (Organosulfur Compounds of Oil from the Urals, Volga River Region, and Siberia), Moscow: Nauka, 1973, p. 247.Google Scholar
  9. 9.
    Ben’kovskii, V.G., Nikitina, V.S., Lyapina, N.K.,et al., Neftekhimiya, 1972, vol. 12, no. 2, p. 271.Google Scholar
  10. 10.
    Boreskov, G.K.,Geterogennyi kataliz v khimicheskoi promyshlennosti (Heterogeneous Catalysis in Chemical Industry), Moscow: Goskhimizdat, 1955, p. 5.Google Scholar
  11. 11.
    Figueras, F., Gomez, R., and Primet, M.,Adv. Chem. Ser., 1973, vol. 121, p. 480.CrossRefGoogle Scholar
  12. 12.
    Chou, P. and Vannice, M.A.,J. Catal., 1987, vol. 107, no. 1, p. 129.CrossRefGoogle Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2000

Authors and Affiliations

  • A. A. Zirka
    • 1
  • A. V. Mashkina
    • 1
  1. 1.Boreskov Institute of Catalysis, Siberian DivisionRussian Academy of SciencesNovosibirskRussia

Personalised recommendations