Abstract
A second ceramic age started in the mid-twentieth century as a new, exciting materials frontier. Electroceramics with phenomenally wide range of electrical resistivity (spread over 30 orders of magnitude) span insulators, semiconductors, metal-like conductors, ionic conductors, and, recently, superconductors. They also include ferroelectrics, piezoelectrics, pyroelectrics and electro-optics beside ferrites. Advances in electroceramics have been fascinating and rapid, leading to unprecedented rates of industrial growth. Age-old limitations of poor mechanical strength and brittleness of ceramics are being overcome by outstanding toughness and strength achieved in zirconiabased ceramics exploiting the martensitic transformation at the tetragonal-monoclinic phase change. The dimensional changes at this transition which prevented the use of zirconia earlier has now been turned into a mechanism for toughening ceramics to significant levels. Ceramics with near-zero overall thermal expansion coefficient offer new opportunities to science and industry.
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References
Aurivillius B 1949Avkiv Kemi 1 463, 499
Aurivillius B 1950Avkiv Kemi 2 519
Buessem W R 1961 inMechanical properties of engineering ceramics (eds) W W Kriegel and H Palmour III (New York: Interscience) p 127
Buessem W R and Tropokowicz T I 1976Ferroelectrics 10 225
Buessem W R, Thielke N R and Sarakausas R V 1952Ceram. Age 60 38
Chowdhury K R and Subbarao E C 1981Ferroelectrics 37 689
Cross L E 1987Ferroelectrics 76 241
Desu S B and Subbarao E C 1980J. Mater. Sci. 15 2113
Desu S B and Subbarao E C 1981Adv. Ceram. 1 189
Garvie R C, Hannik R H J and Pascoe R T 1975Nature (London) 258 703
Goswami A, Buessem W R and Cross L E 1966J. Am. Ceram. Soc. 49 33
Gupta T K, Bechtold H J, Kuznickie R C, Cadoff L H and Rossing B R 1977J. Mater. Sci. 12 2421
Jona F and Shirane G 1962 inFerroelectric crystals (New York: McMillan)
Kenny G R and Bowen H K 1983Am. Ceram. Soc. Bull. 62 590
MRS Bulletin XV(a) 1990 18
Maiti H S and Paria N K 1988 inAdvanced ceramics (ed.) E C Subbarao (Bangalore: Indian Academy of Sciences) p 59
Ohya Y, Nakagawa Z and Hamano K 1987J. Am. Ceram. Soc. 70 C184
Patil R N and Subbarao E C 1969J. Appl. Cryst. 2 281
Rao C N R 1988 inAdvanced ceramics (ed.) E C Subbarao (Bangalore: Indian Academy of Sciences) p 19
Roy R, Agrawal D K and McKinstry H A 1989Ann. Rev. Mat. Sci. 19 59
Schober M 1987Am. Ceram. Soc. Bull. 65 1698
Smolenskii G S, Isupov V A and Agranovskaya A I 1959Sov. Phys.—Solid State Phys. 1 149
Srikanth V and Subbarao E C 1991J. Mater. Res. 6 1308
Srikanth V, Subbarao E C, Agrawal D K, Huang C Y, Roy R and Rao G V 1991aJ. Am. Ceram. Soc. 74 365
Srikanth V, Subbarao E C and Rao G V 1991b (to be published)
Subbarao E C 1959J. Am. Ceram. Soc. 42 279
Subbarao E C 1960J. Am. Ceram. Soc. 43 119
Subbarao E C 1961Phys. Rev. 132 804
Subbarao E C 1962aJ. Am. Ceram. Soc. 45 528
Subbarao E C 1962bJ. Am. Ceram. Soc. 45 166
Subbarao E C 1962cJ. Phys. Chem. Solids 23 665
Subbarao E C (ed.) 1980 inSolid electrolytes and their applications (New York: Plenum Press) p. 1
Subbarao E C 1981Adv. Ceram. 3 1
Subbarao E C 1988aTrans. Indian Ceram. Soc. 46 65
Subbarao E C (ed.) 1988b inAdvanced ceramics (Bangalore: Indian Academy of Sciences) pp 168
Subbarao E C 1990aFerroelectrics 102 267
Subbarao E C 1990bTrans. Indian Ceram. Soc. 49 47
Subbarao E C, Jona F and Shirane G 1960Acta Crystallogr. 13 226
Subbarao E C, Maiti H S and Srivastava K K 1974Phys. Status Solidi 210 9
Subbarao E C and Maiti H S 1988Adv. Ceram. 24 731
Subbarao E C, Banavar J, Bhalla A S, Cross L E, Kurtz S K, Newnham R E and Roy R 1990Phase Transitions 22 157
Tien T Y and Subbarao E C 1963J. Chem. Phys. 39 1041
Wright R E 1972J. Am. Ceram. Soc. 55 54
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Distinguished Materials Scientist of the Year Award Lecture presented at the MRSI meeting, New Delhi, on February 9, 1991.
Professor E C Subbarao, born on 8 August 1928 in Narsapur, Andhra Pradesh received his B.Sc. Tech degree in Glass Technology from Banaras Hindu University, Varanasi in 1949, his B.S. and M.S. degrees in Ceramic Engineering from the University of Washington, Seattle, WA, USA in 1952 and 1953 and his Ph.D. degree in Ceramic Technology from the Pennsylvania State University, University Park, PA, USA in 1957. He was employed by the Parry and Co. Ltd., Ranipet, TN from 1949 to 1951 and as a Research and Fellow Engineer by Westinghouse Research Laboratories, Pittsburgh, Pa, USA from 1956 to 1963. Joining the Metallurgical Engineering Department of the Indian Institute of Technology, Kanpur in 1963 as an Associate Professor, he continued as a Professor from 1964 to 1981. He is the Founder-Director of the Tata Research Development and Design Centre, Pune since 1981. At IIT, Kanpur, he organised the Metallurgical Engineering Department as its first Head from 1963 to 1967 and the Inter-disciplinary Program in Materials Science as its first Convenor from 1971 to 1975. He was also the first Dean of Faculties at IIT, Kanpur from 1966 to 1972. Professor Subbarao published or edited nine books and published over 140 papers. He was elected a Fellow of the Indian National Science Academy, the Indian Academy of Sciences, the Indian Institute of Ceramics, and the (International) Academy of Ceramics. He has been awarded the National Metallurgists Award, the Homi Bhabha Award in Applied Science, and the Varshnei Memorial Award.
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Subbarao, E.C. A second ceramic age—A new materials frontier. Bull. Mater. Sci. 14, 1171–1182 (1991). https://doi.org/10.1007/BF02744610
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DOI: https://doi.org/10.1007/BF02744610