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The spin Hamiltonian for completely anisotropicg-factor and hyperfine coupling tensors

Спиновый Гамильтон иан для полностью ан изотропного g-фактор аи тензоры сверхтонкой связи

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Il Nuovo Cimento B (1971-1996)

Summary

The nature of the approximations underlying the standard methods of interpreting anisotropic electron spin resonance spectra of single crystals are explicated. Equations are derived for an unpaired electron interacting with a spin-1/2 nucleus when both the electronicg-factor and the hyperfine interactionT are anisotropic.

Riassunto

Si esplicita la natura delle approssimazioni che stanno alla base dei metodi usuali di interpretare gli spettri di risonanza di spin elettronioo anisotropo. Si deducono le equazioni per un elettrone non accoppiato che interagisce con un nucleo di spin 1/2 quando sia il fattoreg elettronico che l’interazione iperfinaT sono anisotrope.

Резюме

Объясняется природа приближений, лежащих в основестандартных методов интерпретац ии спектров анизотро пного электронного спинового резонанса в монокри сталлах. Выводятся у равнения для неспаре нного электрона, взаимодействующего с ядром со спином 1/2, ког да и электронный g-фак тор и сверхтонкое вз аимодействие Т являю тся анизотропными.

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References

  1. M. H. L. Pryce:Nature,164, 116 (1949).

    Article  ADS  Google Scholar 

  2. B. Bleaney:Phil. Mag.,42, 441 (1951).

    Article  Google Scholar 

  3. J. E. Geusic andL. C. Brown:Phys. Rev.,112, 64 (1958).

    Article  ADS  Google Scholar 

  4. A. D. McLachlan:Mol. Phys.,1, 233 (1958).

    Article  ADS  Google Scholar 

  5. I. Miyagawa andW. Gordy:Journ. Chem. Phys.,30, 1590 (1959).

    Article  ADS  Google Scholar 

  6. D. S. Schonland:Proc. Phys. Soc.,73, 788 (1959).

    Article  ADS  Google Scholar 

  7. H. M. McConnell andJ. Strathdee:Mol. Phys.,2, 129 (1959).

    Article  ADS  Google Scholar 

  8. H. M. McConnell, C. Heller, T. Cole andR. W. Fessenden:Journ. Amer. Chem. Soc.,82, 766 (1960).

    Article  Google Scholar 

  9. I. Miyagawa andW. Gordy:Journ. Chem. Phys.,32, 255 (1960).

    Article  ADS  Google Scholar 

  10. J. A. Weil andJ. H. Anderson:Journ. Chem. Phys.,28, 864 (1958).

    Article  ADS  MATH  Google Scholar 

  11. A. Lund andT. Vänngard:Journ. Chem. Phys.,42, 2979 (1965).

    Article  ADS  Google Scholar 

  12. A. Carrington andA. D. Mclachlan:Introduction to Magnetic Resonance (New York, 1967), p. 102.

  13. W. Bernhard andW. Snipes:Journ. Chem. Phys.,44, 2817 (1966).

    Article  ADS  Google Scholar 

  14. C. P. Poole jr. andH. A. Farach:Adv. Mag. Res., in press.

Download references

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Farach, H.A., Poole, C.P. The spin Hamiltonian for completely anisotropicg-factor and hyperfine coupling tensors. Nuov Cim B 4, 51–58 (1971). https://doi.org/10.1007/BF02737563

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  • DOI: https://doi.org/10.1007/BF02737563

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