Abstract
The damage of glasses upon multiple exposure to “prethreshold” laser pulses results from the gradual modification of glass properties toward a decrease in the optical strength. Depending on the band gap and the radiation wavelength, the prevailing prethreshold process is either color center formation or the breaking of chemical bonds in the glass-forming network. In the latter case, the resistance of a material to laser irradiation is determined to a large measure by the connectivity and homogeneity of the network at the nanostructural level.
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Gomelauri, G.V., Epifanov, A.S., Manenkov, A.A., and Prokhorov, A.M., Statistical Features of Cumulative Ionization of Wide-Gap Dielectrics by Laser Radiation under Deficiency of Initiating Electrons,Zh. Eksp. Teor. Fiz., 1980, vol. 79, no. 6, pp. 2356–2361.
Gorshkov, B.G., Danileiko, Yu.K., Nikolaev, V.N., and Sidorin, A.V., Effect of Multiple Irradiation upon Exposure of Optical Material to Laser Radiation,Kvantovaya Elektron. (Moscow), 1983, vol. 10, no. 3, pp. 640–643.
Merkle, L.D., Bass, M., and Swimm, R.T., Multiple Pulse Laser-induced Damage in Crystalline and Fused Quartz at 1.06 and 0.532 Μm,Opt. Eng. (Bellingham, Wash.), 1983, vol. 22, no. 4, pp. 405–411.
Glebov, L.B., Efimov, O.M., and Petrovskii, G.T., The Absence of Prethreshold Ionization and Cumulative Effect upon Multiple Exposure of Glasses to Laser Radiation,Kvantovaya Elektron. (Moscow), 1986, vol. 13, no. 9, pp. 1897–1901.
Glebov, L.B., Efimov, O.M., Petrovskii, G.T., and Rogovtsev, P.N., Effect of Mode Composition of Laser Radiation on the Optical Breakdown in Silicate Glasses,Kvantovaya Elektron. (Moscow), 1984, vol. 11, no. 2, pp. 330–334.
Kitriotis, D. and Merkle, L.D., Multiple-Pulse Laser-induced Damage Phenomena in Silicates,Appl. Opt., 1989, vol. 28, no. 5, pp. 949–958.
Balitskas, S.K., Lukoshis, I.P., Maldutis, E.K., Sakalauskas, S.V., and Yatsinavichus, S.I., Multiple Pulse Laser-induced Prethreshold Changes and Damage in Optical Glasses,Izv. Akad. Nauk SSSR, Ser. Fiz., 1989, vol. 53, no. 3, pp. 431–438.
Glebov, L.B., Dokuchaev, V.G., Efimov, O.M., Nikonorov, N.V., and Petrovskii, G.T., Role of Radiation-induced Color Centers in the Development of Optical Breakdown in Silicate Glasses,Izv. Akad. Nauk SSSR, Ser. Fiz., 1985, vol. 49, no. 4, pp. 1179–1181.
Von der Linde, D. and Schuler, H., Breakdown Threshold and Plasma Formation in fs Laser-Solid Interaction,J. Opt. Soc. Am. B: Opt. Phys., 1996, vol. 13, no. 1, pp. 216–221.
Chmel, A., Fatigue Laser-induced Damage in Transparent Materials,Mater. Sci. Eng., B, 1997, vol. 49, no. 1, pp. 175–190.
Bosyi, O.N. and Efimov, O.M., Regularities and Mechanism of Cumulative Effect in the Absence of Prethreshold Ionization of a Glass Matrix,Kvantovaya Elektron. (Moscow), 1996, vol. 23, no. 8, pp. 737–742.
Bosyi, O.N., Efimov, O.M., and Mekryukov, A.M., Investigation of Optical Parameters for Silicate Glasses under Exposure to Laser Radiation,Izv. Akad. Nauk SSSR, Ser. Fiz., 1990, vol. 54, no. 6, pp. 1109–1113.
Gusev, G.P., Musienko, T.I., Petrovskii, G.T., Savanovich, L.P., and Shatilov, A.V., Statistics of Damages of Microinhomogeneities in Optical Materials upon Multiple Exposure to Light,Opt.-Mekh. Prom-st., 1981, no. 8, pp. 35–37.
Balitskas, S.K. and Maldutis, E.K., Multiple Pulse Laser-induced Bulk Damage in Optical Glasses,Kvantovaya Elektron. (Moscow), 1981, vol. 8, no. 4, pp. 902–906.
Merkle, L.D. and Kitriotis, D., Temperature Dependence of Laser-induced Bulk Damage in SiO2 and Borosilicate Glass,Phys. Rev. B: Condens. Matter, 1988, vol. 38, no. 2, pp. 1473–1482.
Merkle, L.D., Koumvaklis, N., and Bass, M., Laser-induced Damage in SiO2 at 1.064, 0.532, and 0.355 Μm,J. Appl. Phys., 1984, vol. 55, no. 3, pp. 772–779.
Kondyrev, A.M., Bugaev, A.A., Eron’ko, S.B., and Chmel’, A., Cumulative Effect in Optical Damage of Transparent Dielectrics,Fiz. Tverd. Tela (Leningrad), 1988, vol. 30, no. 6, pp. 1868–1870.
Kytina, I.G. and Kinber, V.E., On the Fatigue Damage in Glasses under Laser Irradiation,Kvantovaya Elektron. (Moscow), 1980, vol. 7, no. 11, pp. 2427–2431.
Zhurkov, S.N., Eron’ko, S.B., and Chmel’, A., Thermofluctuation Nature of Optical Resistance of Transparent Dielectrics,Fiz. Tverd. Tela (Leningrad), 1982, vol. 24, no. 3, pp. 733–739.
Zhurkov, S.N., Kondyrev, A.M., Petrov, V.A., and Chmel’, A.E., Thermofluctuation Nature of Optical Resistance of Transparent Solids,Philos. Mag., 1988, vol. 57, no. 2, pp. 307–317.
Gagarin, A.P., Glebov, L.B., Dokuchaev, V.G., Efimov, O.M., Popova, L.B., and Tolstoi, M.N., The Influence of Absorbing Impurities on the Optical Breakdown in Transparent Dielectrics,Zh. Tekh. Fiz., 1980, vol. 52, no. 1, pp. 101–104.
Glebov, L.B., Efimov, O.M., Petrovskii, G.T., and Rogovtsev, P.N., Optical Breakdown in Silicate Glasses upon Two-Photon Absorption of Laser Radiation,Kvantovaya Elektron. (Moscow), 1983, vol. 10, no. 7, pp. 1490–1492.
Hopper, R.W. and Ulmann, D.R., Mechanism of Inclusion Damage in Laser Glass,J. Appl. Phys., 1970, vol. 41, no. 10, pp. 4023–4037.
Koldunov, M.F., Manenkov, A.A., and Pokotilo, I.L., Regularities of Laser-induced Damage Initiated by Absorbing Inclusions of Different Types in Transparent Solids,Kvantovaya Elektron. (Moscow), 1998, vol. 25, no. 9, pp. 833–837.
Gagarin, A.P., Glebov, L.B., Efimov, O.M., and Efimova, O.S., Color Center Formation in Sodium-Potassium Silicate Glass upon Nonlinear Absorption of Powerful UV Radiation,Fiz. Khim. Stekla, 1979, vol. 5, no. 2, pp. 378–380.
Vlasov, D.V., Glebov, L.B., Efimov, O.M., Korobkin, V.V., Prokhorov, A.M., Tolstoi, M.N., and Shchebnev, E.P., Nonlinear Coloration and Laser-induced Damage of Lead Silicate Glasses upon Multiphoton Absorption,Izv. Akad. Nauk SSSR, Ser. Fiz., 1981, vol. 45, no. 4, pp. 924–928.
Glebov, L.B., Efimov, O.M., and Petrovskii, G.T., The Absence of Prethreshold Ionization and Cumulative Effect upon Multiple Exposure of Glass to Laser Radiation,Kvantovaya Elektron. (Moscow), 1986, vol. 13, no. 9, pp. 1897–1901.
Glebov, L.B., Dokuchaev, V.G., Nikonorov, N.V., and Petrovskii, G.T., A Novel Effect upon Laser Irradiation of Glasses,Dokl. Akad. Nauk SSSR, 1984, vol. 274, pp. 568–571.
Jones, S.C., Braunlich, P., Casper, R.T., and Shen, X.-A., Recent Progress on Laser-induced Modifications and Intrinsic Bulk Damage of Wide-Gap Optical Materials,Opt. Eng. (Bellingham, Wash.), 1989, vol. 28, no. 10, pp. 1039–1068.
Braunlich, P., Jones, S.C., Shen, X.-A., and Casper, R.T., Laser-induced Modification and the Mechanism of Intrinsic Damage in Wide Gap Optical Materials,Nucl. Instrum. Methods Phys. Res., Sect. B, 1990, vol. 46, nos. 1-4, pp. 224–230.
Glebov, L.B., Efimov, O.M., Petrovskii, G.T., and Rogovtsev, P.N., The Influence of Photobleaching on Two-Photon Coloration of Sodium Silicate Glasses,Fiz. Khim. Stekla, 1984, vol. 10, no. 1, pp. 66–70.
Bosyi, O.N. and Efimov, O.M., Regularities and Mechanism of Cumulative Effect upon Multiphoton Generation of Color Centers,Kvantovaya Elektron. (Moscow), 1996, vol. 23, no. 8, pp. 729–736.
Vasil’ev, L.A.,Tenevye metody (Shadow Methods), Moscow: Nauka, 1968.
Austin, R.R., Michaud, R., Guenther, A.H., and Putman, J., Effect of Structure, Composition and Stress on the Laser Damage Threshold,Appl. Opt., 1973, vol. 12, no. 4, pp. 665–668.
Chmel, A., Kondyrev, A.M., Muchina, L.L., and Proyanenkov, V.V., Optical Strength of Ion Exchange Treated Glass,Glass Technol., 1995, vol. 36, no. 2, pp. 51–53.
Eron’ko, S.B., Zhurkov, S.N., and Chmel’, A., Kinetics of Accumulation of Damages in Transparent Dielectrics upon Multiple Laser Irradiation,Fiz. Tverd. Tela (Leningrad), 1978, vol. 20, no. 12, pp. 3570–3574.
Kusov, A., Kondyrev, A., and Chmel, A., Common Approach to the Problem of Defect Nucleation in Solids under “Pre-Threshold” Laser Irradiation,J. Phys.: Condens. Matter, 1990, vol. 2, no. 9, pp. 4064–4080.
Chmel’, A., Eron’ko, S.B., Kondyrev, A.M., and Savel’ev, V.N., Kinetics of Accumulation of Microdefects upon Exposure of Transparent Dielectrics to Optical Radiation,Fiz. Tverd. Tela (Leningrad), 1986, vol. 28, no. 4, pp. 1071–1075.
Balitskas, S.K. and Maldutis, E.K., Cumulative Character of Laser-induced Damage in Optical Glasses,Izv. Akad. Nauk SSSR, Ser. Fiz., 1985, vol. 49, no. 6, pp. 1076–1083.
Greco, F.G. and Martinelly, T.A., Compositional Dependency of Laser-induced Damage in Glass,J. Am. Ceram Soc., 1967, vol. 50, no. 5, pp. 270–271.
Aleshin, I.V., Dvornikov, G.D., Imas, Ya.A., Proshin, V.I., Salyadinov, V.S., and Shatilov, A.V., Relation between Thresholds of Optical Breakdown in Glasses and Their Structure,Opt.-Mekh. Prom-st., 1975, no. 3, pp. 17–19.
Hack, H. and Neuroth, N., Resistance of Optical and Coloured Glasses to 3-nsec Laser Pulses,Appl. Opt., 1982, vol. 21, no. 18, pp. 3239–3248.
Karapetyan, G.O. and Maksimov, L.V., Relation of Chemically Inhomogeneous Glass Structure and Optical Breakdown Threshold,Kvantovaya Elektron. (Moscow), 1984, vol. 11, no. 9, pp. 1840–1841.
Eron’ko, S.B., Kuksenko, K.N., and Chmel’, A., Manifestation of Optical Radiation-induced Surface Modification of Activated Glasses in IR spectra,Fiz. Khim. Stekla, 1978, vol. 4, no. 1, pp. 121–124.
Eron’ko, S.B. and Chmel’, A., Initial Stage of Damage of Glass Surface upon Multiple Exposure to Light,FizKhim. Stekla, 1978, vol. 6, no. 4, pp. 498–500.
Chmel, A. and Eronko, S.B., Laser-induced Generation of Structural Defects in Vitreous Silica and in Activated Silicate Glass,J. Non-Cryst. Solids, 1985, vol. 70, no. 1, pp. 45–53.
Eron’ko, S.B., Suvorov, A.V., and Chmel’, A., Influence of Breakages in Silicate Network of Amorphous Silica on Its Optical Strength,Fiz. Khim. Obrab. Mater, 1981, no. 2, pp. 151–153.
Borodina, T.V., Kharshak, A.A., and Chmel’, A.E., Strength of Optical Fiber Waveguides Fabricated from Preforms with Structurally Inhomogeneous Layer,Fiz. Khim. Stekla, 1991, vol. 17, no. 1, pp. 208–210.
Chmel, A., Baptizmanski, V.V., and Kharshak, A.A., Influence aes defauts de la structure du verre sur la resistance mecanique des fibres pptiques,J. Phys. III, 1992, vol. 2, no. 12, pp. 2387–2396.
Chmel, A. and Eronko, S.B., Optical Strength of Glasses Implanted with Argon Ions,Glass Technol., 1998, vol. 39, no. 1, pp. 32–34.
Polato, P., Mazoldi, P., and Boscolo Boscoletto, A., Characterization by Nuclear and Spectrometric Analysis of Near-Surface Modifications of Glass Implanted with Heavy Ions,J. Am. Ceram. Soc., 1987, vol. 70, no. 10, pp. 775–779.
Stuart, B.C., Feit, M.D., Rubenchik, A.M., Shore, B.W., and Perry, M.D., Laser-induced Damage in Dielectrics with Nanosecond to Subpicosecond Pulses,Phys. Rev. Lett., 1995, vol. 74, no. 12, pp. 2248–2251.
Zhurkov, S.N., Kinetic Concept of the Strength of Solids,Int. J. Mech., 1965, vol. 1, no. 1, pp. 311–317.
Manenkov, A.A., Matyushin, G.A., Nechitailo, V.S., Prokhorov, A.M., and Tsaprilov, A.S., On the Nature of Cumulative Effect in Laser-induced Damage of Optical Materials,Kvantovaya Elektron. (Moscow), 1983, vol. 10, no. 12, pp. 2426–2432.
Giuliano, C.R., Laser-induced Damage in Transparent Dielectric Materials,Appl. Phys. Lett., 1964, vol. 7, no. 7, pp. 137–139.
Lokhov, Yu.N. and Fiveiskii, Yu.D., Some Aspects of Laser-induced Hypersound Generation upon Stimulated Brillouin Scattering,Zh. Prikl. Spektrosk., 1971, vol. 15, no. 2, pp. 219–222.
Haiwu Yu and Shaoxian Meng, Transient Stimulated Brillouin Scattering and Damage of Optical Glass,J. Appl. Phys., 1997, vol. 81, no. 1, pp. 89–94.
Montes, C. and Pellat, R., Inertial Response to Nonstationary Stimulated Brillouin Backscattering: Damage of Optical and Plasma Fibers,Phys. Rev. A: At., Mol., Opt. Phys., 1987, vol. 36, no. 6, pp. 3976–3979.
De Sivestri, S. and Svelto, O., Quick as a Flash: Ultrashort Laser Sources,Europhys. News, 1998, vol. 29, no. 4, pp. 149–150.
Niemz, M.H., Threshold Dependence of Laser-induced Optical Breakdown on Pulse Duration,Appl. Phys. Lett., 1996, vol. 66, no. 10, pp. 1181–1185.
Saeta, P.N. and Greene, B.I., Primary Relaxation Process at the Band Edge of SiO2,Phys. Rev. Lett, 1993, vol. 70, no. 23, pp. 3588–3591.
Kautec, W., Krüger, J., Lenzner, M., Sartania, S., Spielmann, C., and Krausz, F., Laser Ablation of Dielectrics with Pulse Durations between 20 fs and 3 ps,Appl. Phys. Lett., 1996, vol. 69, no. 21, pp. 3146–3148.
Varel, H., Ashkenasi, D., Rosenfeld, A., Hermann, R., Noach, F., and Campbell, E.E.B., Laser-induced Damage in SiO2 and CaF2 with Picosecond and Femtosecond Pulses,Appl. Phys. A: Matter Sci. Proc, 1996, vol. 62, no. 3, pp. 293–294.
Andebert, P., Daguzan, Ph., Dos Santos, A., Grauthier, J.C., Greinfre, J.P., Guizard, S., Hamoniaux, G., Krastev, K., Martin, P., Petite, G., and Antonetti, A., Space-Time Observation of an Electron Gas in SiO2,Phys. Rev. Lett., 1994, vol. 73, no. 14, pp. 1990–1993.
Lenzner, M., Krüger, J., Sartania, S., Cheng, Z., Spielmann, Ch., Mourou, G., Kautec, W., and Kraus, F., Femtosecond Optical Breakdown in Dielectrics,Phys. Rev. Lett., 1998, vol. 80, no. 18, pp. 4076–4079.
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Chmel’, A.E. Cumulative effect in laser-induced damage of optical glasses: A review. Glass Phys Chem 26, 49–58 (2000). https://doi.org/10.1007/BF02731943
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DOI: https://doi.org/10.1007/BF02731943