Summary
We present in this paper an explanation, based on the properties of the Racah operators and the Wigner coefficients, of a set of rules which have been recently proposed for the solution of the quantitative problem of the splitting of a degenerate level.
Riassunto
In questo lavoro si fornisce una spiegazione di un insieme di regole recentemente proposte per risolvere il problema della separazione dei livelli degeneri basata sulle proprietà degli operatori di Racah e dei coefficienti di Wigner.
Резюме
В этой работе мы предлагаем объяснение, основанное на свойствах операторов Рака и коэффициентов Вигнера, для системы правил, которые были недавно предложены для решения количественной проблемы расщепления вырожденного уровня.
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References
See for example the splitting of anL=3 level under a crystal field of octohedral symmetry. This problem is worked out in detail using perturbation theory inT. Kahan:Théorie des groupes en physique classique et quantique, Tome III (Paris, 1972), p. 237.
L. C. Biedenharn andA. Gamba:Rev. Brasil. Fis.,2, 319 (1972).
M. Rotenberg, R. Bivins, N. Metropolis andJ. K. Wooten:The 3-j and 6-j symbols (Cambridge, Mass., 1959), p. 5.
See for example ref. (3)M. Rotenberg, R. Bivins, N. Metropolis andJ. K. Wooten:The 3-j and 6-j symbols (Cambridge, Mass., 1959), p. 5. for a summary of the properties of 3-j symbols.
The arbitrariness in normalization for the coefficientsa kq does not mean, of course, that the physical potentialV can be manipulated at will. For suppose that we would multiply all thea kq (k fixed) by a common factor β, then we would have to choose α ′ k =α k /β in eq. (1) in order to leaveV invariant.
In this connection see a very interesting paper byA. J. Van Zanten andE. de Vries:Tensor operators of finite groups, preprint (1973), where a complete reference list on the subject is reported.
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Basano, L., Cenni, R. Atomic level splitting by external fields. Nuov Cim B 22, 261–272 (1974). https://doi.org/10.1007/BF02726592
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DOI: https://doi.org/10.1007/BF02726592