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Comparative studies of a single cell and a stack of direct methanol fuel cells

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Abstract

Comparative studies have been conducted to observe the characteristics of a single cell and a stack of direct methanol fuel cells (DMFC) at ambient conditions. The maximum power density of a single cell was about 70 mW/ cm2 at 2M methanol (CH3OH) of 3.75 cc/min and dry air of 250 cc/min at room temperature and atmospheric pressure. In a stack, on the other hand, the maximum power density of the stack was 85mW/cm2 which was about a 20% higher value. This could be attributed to higher internal temperature than that of the single cell: the temperature of single cell increased up to 35 °C, while the highest temperature of the stack was 69 °C. This is because the cell temperature in DMFC was autonomously increased by exothermal reaction such as chemical oxidation of CH3OH and oxygen reduction. The temperature was strongly dependent on the number of unit cells in a stack and the amount of electric load applied. In DMFC stacks, the performance of an individual cell showed uneven distribution when the electric load was increased and it was mostly influenced by different local concentration of reactants and non-uniform temperature

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References

  • Amphlett, J. C., Peppley, B. A., Halliop, E. and Sadiq, A., “The Effect of Anode Flow Characteristics and Temperature on the Performance of a Direct Methanol Fuel Cell,”J. Power Sources,96, 204 (2001).

    Article  CAS  Google Scholar 

  • Argyropoulos, P., Scott, K. and Taama, W.M., “Engineering Aspects of the Direct Methanol Fuel Cell System,”J. Power Sources,79, 43 (1999).

    Article  Google Scholar 

  • Blum, A., Duvdevani, T., Philosoph, M., Rudoy, N. and Peled, E., “Waterneutral Micro Direct-methanol Fuel Cell (DMFC) for Portable Applications,”J. Power Sources,117, 22 (2003).

    Article  CAS  Google Scholar 

  • Carrette, L., Friedrich, K. A. and Stimming, U., “Anodenstruktur Für Interne Methanreformierung,”Fuel Cells,1, 5 (2001).

    Article  CAS  Google Scholar 

  • Kim, D., Cho, E. A., Hong, S.-A., Oh, I.-H. and Ha, H.Y., “Recent Progress in Passive Direct Methanol Fuel Cells at KIST,”J. Power Sources,130, 172 (2004).

    Article  CAS  Google Scholar 

  • McNicol, B.D., Rand, D. A. J. and Williams, K.R., “Fuel Cells for Road Transportation Purposes — Yes or No?,”J. Power Sources,100, 47 (2001).

    Article  CAS  Google Scholar 

  • Ren, X. and Gottesfeld, S., “Electro-osmotic Drag of Water in Poly(perfluorosulfonic acid) Membranes,”J. Electrochem. Soc.,148, A87 (2001).

    Article  CAS  Google Scholar 

  • Savadogo, O., “Hydrogen/Oxygen Polymer Electrolyte Membrane Fuel Cell (PEMFC) Based on Acid-doped Polybenzimidazole (PBI),”New Mater. Electrochem. Syst.,1, 47 (1998).

    CAS  Google Scholar 

  • Scott, K., Taama, W.M., Argyropoulos, P. and Sundmacher, K., “The Impact of Mass Transport and Methanol Crossover on the Direct Methanol Fuel Cell,”J. Power Sources,83, 204 (1999).

    Article  CAS  Google Scholar 

  • Scott, K., Taama, W.M., Kramer, S. and Argyropoulos, P., “Limiting Current Behaviour of the Direct Methanol Fuel Cell,”Electrochim. Acta,45, 945 (1999).

    Article  CAS  Google Scholar 

  • Tüber, K., Oedegaard, A., Hermann, M. and Hebling, C., “Investigation of Fractal Flow-fields in Portable Proton Exchange Membrane and Direct Methanol Fuel Cells,”J. Power Sources,131, 175 (2004).

    Article  Google Scholar 

  • Tüber, K., Pócza, D. and Hebling, C., “Visualization of Water Buildup in the Cathode of a Transparent PEM Fuel Cell,”J. Power Sources,124, 403 (2003).

    Article  Google Scholar 

  • Zawodzinski, T.A., Derouin, C., Radzinski, S., Sherman, R. J., Smith, V. T., Springer, T. E. and Gottesfeld, S., “Water Uptake by and Transport through Nafion 117 Membranes,”J. Electrochem. Soc.,140, 041 (1993).

    Article  Google Scholar 

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Correspondence to Heung Yong Ha.

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Lee, S., Kim, D., Lee, J. et al. Comparative studies of a single cell and a stack of direct methanol fuel cells. Korean J. Chem. Eng. 22, 406–411 (2005). https://doi.org/10.1007/BF02719419

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  • DOI: https://doi.org/10.1007/BF02719419

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