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Photocatalytic degradation of toluene with ozone addition

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Abstract

The main goal of this study is to analyze the characteristics of photodegradation and photocatalytic activation experimentally with the major parameters such as air flow rate, inlet toluene concentration, ozone concentration, UV light and bead material, etc. In particular, the effects of transmissivity of UV radiation with TiO2 coated supporter (bead material) and void fraction (bead size) on the photocatalytic degradation are estimated for TiO2/UV and O3/TiO2/UV process. In results, the experiment shows that the UV light transmissivity of 5mm glass bead becomes much higher than that of 6.5 mm alumina bead in spite of lower void fraction inducing the higher photoactivation. The conversion of toluene represents about 96% during reaction time 420 min at the toluene concentration of 100 ppm and ozone concentration of 2.5 ppm, showing a conversion rate of ozone of 95% for O3/TiO2/UV process.

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References

  • d’Hennezel, O., Pichat, P. and Ollis, D. F., “Benzene and Toluene Gasphase Photocatalytic Degradation over H2O and HCL Pretreated TiO2: By-products and Mechanisms,”J. Photochemistry and Photobiology A : Chemistry,118, 197 (1998).

    Article  CAS  Google Scholar 

  • Kang, J.W., Lee, K. H., Koh, C. I. and Nam, S.N., “The Kinetics of the Sonochemical Process for the Destruction of Aliphatic and Aromatic Hydrocarbons,”Korean J. Chem. Eng.,18(3), 336 (2001).

    Article  CAS  Google Scholar 

  • Lee, H. J., Kang, D.W. and Chi, J., “Degradation Kinetics of Recalcitrant Organic Compounds in a Decontamination Process with UV/H2O2 and UV/H2O2/TiO2 Processes,”Korean J. Chem. Eng.,20(3), 503 (2003).

    Article  CAS  Google Scholar 

  • Lixin, C., “Photocatalytic Oxidation of Toluene on Nanoscale TiO2 Catalysts: Studies of Deactivation and Regeneration,”J. Catalysts,196, 253 (2000).

    Google Scholar 

  • Luo, Y. and Ollis, D. F., “Heterogeneous Photocatalytic Oxidation of TCE and Toluene Mixture in air: Kinetic Promotion and Inhibition, Time-Dependent Catalyst Activity,”J. Catalysis,163, 1 (1996).

    Article  CAS  Google Scholar 

  • Mizuno, A., Yamazaki, Y., Ito, H. and Yoshida, H., “AC Energized Ferroelectric Pellet Bed Gas Cleaner,”IEEE Transactions on Industry Applications,28, 535 (1992).

    Article  CAS  Google Scholar 

  • Park, D. R., Ahn, B. J., Park, H. S., Yamashita, H. and Masakazu, A., “Photocatalytic Oxidation of Ethylene to CO2 and H2O on Ultrafine Powered TiO2 Photocatalysts: Effects of the Presence of O2 and H2O and the Addition of Pt,”Korean J. Chem. Eng.,18, 930 (2001).

    Article  CAS  Google Scholar 

  • Shen, Y. S. and Ku, Y., “Decomposition of Gas-phase TCE by the UV/ TiO2 Process in the Presence of Ozone,”Chemosphere,46, 101 (2002).

    Article  CAS  Google Scholar 

  • Vincenzo, A., Coluccia, S. and Loddo, V., “Photocatalytic Oxidation of Gaseous Toluene on Anatase TiO2 Catalyst: Mechanistic Aspects and FT-IR Investigation,”Applied Catalysis B : Environmental,20, 15 (1999).

    Article  Google Scholar 

  • Wonyong, C., “Investigation on TiO2-coated Optical Fibers for Gasphase Photocatalytic Oxidation of Acetone,”Applied Catalysis B: Environmental,31, 209 (2001).

    Article  Google Scholar 

  • Xianyu, W. X., Park, M. K. and Lee, W. I., “Thickness Effect in the Photocatalytic Activity of TiO2 Thin Films Derived from Sol-Gel Process,”Korean J. Chem. Eng.,18(6), 903 (2001).

    Article  CAS  Google Scholar 

  • Xiaoli, Y., Huixiang, S. and Dahui, W., “Photoelectrocatalytic Degradation of Phenol Using a TiO2/Ni Thin-film Electrode,”Korean J. Chem. Eng.,20(4), 679 (2003).

    Article  Google Scholar 

  • You, Y. S., Chung, K. H., Kim, J. H. and Seo, G., “Photocatalytic Oxidation of Toluene over TiO2 Catalysts Supported on Glass Fiber,”Korean J. Chem. Eng.,18, 924 (2001).

    Article  CAS  Google Scholar 

  • Zhang, Pengyi, “A Comparative Study on Decomposition of Gaseous Toluene by O3/UV, TiO2/UV and O3/TiO2/UV,”Journal of Photochemistry and Photobiology A: Chemistry,6219, 1 (2003).

    Article  Google Scholar 

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Correspondence to Seok-Jun Yoa.

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Yoa, SJ., Cho, YS. & Kim, JH. Photocatalytic degradation of toluene with ozone addition. Korean J. Chem. Eng. 22, 364–369 (2005). https://doi.org/10.1007/BF02719412

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  • DOI: https://doi.org/10.1007/BF02719412

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