Skip to main content

Removal of nitrogen oxides from air by chemicals-impregnated carbons

Abstract

Fixation of nitrogen oxides (NOx) in air onto granular activated carbon impregnated with chemicals was attempted to improve removal efficiency of NOx by activated carbon adsorption. Nitric oxide (NO) and nitrogen dioxide (NO2), were tried to remove by a flow test. Fixed-bed adsorption breakthrough curves were obtained when some kinds of carbon were used. The amount adsorbed of NO2 changed with the amount and kinds of metallic salts impregnated. Chemicals-impregnated carbons were prepared from a commercial activated carbon. Among obtained carbons, the one which showed the highest selectivity for NOx was chosen, and its performance with the change in humidity was determined. Removal mechanism of NO2 was estimated, and the carbon impregnated with potassium hydroxide was found to be superior to any other carbon tested. The amount of the adsorbed NO and that produced by the reduction of NO2 were determined from the breakthrough curves.

This is a preview of subscription content, access via your institution.

References

  • Gray, P. G. and Do, D. D., “Modelling of the Interaction of Nitrogen Dioxide with Activated Carbon I. Adsorption Dynamics at the Single Particle Scale”,Chem. Eng. Comnu,117, 219 (1992).

    Article  CAS  Google Scholar 

  • Hashida, I. and Nishimura, M., “Adsorption of Nitrogen Dioxide on Various Poly(vinylpyridine) Resins with Porous Structure”,Nippon Kagaku Kaishi,2, 383 (1975).

    Google Scholar 

  • Inui, T., Otowa, T. and Takegami, Y., “Complete Conversion of NO over the Composite Catalyst Supported on Active Carbon”,Ind. Eng. Chem. Prod. Res Dev.,21, 56 (1982).

    Article  CAS  Google Scholar 

  • Kaneko, K., Ozeki, S. and Inoue, K., “The Adsorption of Nitrogen Monoxide on Iron-treated Activated Carbon Fibers”,Nippon Kagaku Kaishi,7, 1351 (1985).

    Google Scholar 

  • Kapteijn, F., Mierop, A. J. C, Abbel, G. and Moulijn, J. A., “Reduction of NOx over Alkali Metal-Carbon Systems”,J. Chem. Soc, Chem. Commun., 1085 (1984).

  • Mochida, I., Fujitsu, H., Shiraishi, I. and Ida, S., “Catalytic Activities of an Active Carbon and a PAN-ACF for the Reduction of Nitrogen Monoxide with Ammonia”,Nippon Kagaku Kaishi,5, 797 (1987).

    Google Scholar 

  • Mochida, I., Mizojiri, N., Fujitsu, H., Komatsubara, Y. and Ida, S., “Reaction of Nitrogen Monoxide with Ammonia over a Series of Pan-Based Active Carbon Fibers (PAN-ACF) Treated with Sulfuric Acid”,Nippon Kagaku Kaishi,9, 1676 (1985a).

    Google Scholar 

  • Mochida, I., Ogaki, M., Fujitsu, H., Komatsubara, Y. and Ida, S., “Mechanism in the Reduction of Nitrogen Monoxide with Ammonia on the Coke Activated with Sulfuric Acid”,Nippon Kagaku Kaishi,4, 680 (1985b).

    Google Scholar 

  • Mochida, I., Ogaki, M., Fujitsu, H., Komatsubara, Y. and Ida, S., “Reduction of Nitric Oxide with Activated PAN Fibers”,Fuel,64, 1054 (1985c).

    Article  CAS  Google Scholar 

  • Mochida, I., Sun, Y. N., Fujitsu, H., Kisamori, S. and Kawano, S., “Reduction of Nitrogen Monoxide by Active Carbon Fibers Impregnated with Metalic Salts”,Nippon Kagaku Kaishi,6, 885 (1991).

    Google Scholar 

  • Mochida, I., Yata, K., Fujitsu, H. and Komatsubara, Y., “Catalytic Activity of Cupper (II) Salt of Heteropolyphosphoric Acid for the Reduction of NO with Its Supporting Active Carbon”,Bull Chem. Soc. Jpn.,58, 900 (1985d).

    Article  CAS  Google Scholar 

  • Naruse, Y., Hata, T. and Kishihata, H., “Oxidative Adsorption of Nitrogen Monoxide on Zeolite”,Nippon Kagaku Kaishi,3, 413 (1979).

    Google Scholar 

  • Okuhara, T. and Tanaka, K., “Adsorption and Reduction of Nitrogen Monoxide by Potassium-doped Carbon”,J. Chem. Soc, Faraday Trans. 1,82, 3657 (1986).

    Article  CAS  Google Scholar 

  • Takeuchi, Y., Ikeda, H. and Asaba, H., “Removal of H2S, CH3SH and (CH3)3N from Air by Use of Chemically Treated Activated Carbon”,J. Chem. Eng. Jpn.,21(6), 91 (1988).

    Google Scholar 

  • Urano, K., Tanikawa, N., Masuda, T. and Kobayashi, Y., “Adsorption of Nitrogen Dioxide on Activated Carbon”,Nippon Kagaku Kaishi,1, 124 (1977).

    Google Scholar 

  • Yamashita, H., Yamada, H. and Tomita, A., “Reaction of Nitric Oxide with Metal-loaded Carbon in the Presence of Oxygen”,Applied Catalysis,78, L1 (1991).

    Article  CAS  Google Scholar 

  • Yanai, H., “Production of Activated Carbon and Its Industrial Application”,Bunrigijutu (Separation Technology),13(6), 363 (1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Takeuchi, Y., Yanagisawa, K., Tanaka, Y. et al. Removal of nitrogen oxides from air by chemicals-impregnated carbons. Korean J. Chem. Eng. 14, 377–381 (1997). https://doi.org/10.1007/BF02707055

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02707055

Key words

  • Adsorption
  • Chemicals-Impregnated Carbon
  • Evolution Ratio of NO NOx Removal
  • Reduction Ratio