Skip to main content
Log in

Impact and threshold concentration of toxic materials in the stripped gas liquor on nitrification

  • Articles
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

The impact of the threshold concentration of toxic materials on nitrification in stripped gas liquor was investigated. Ammonia nitrogen, phenol, thiocyanide, cyanide, m-cresol, toluene, quionoline, and aniline were selected as toxic materials in the wastewater treatment experiments. The concentrations of organic materials that are contained in raw wastewater of stripped gas liquor were 400 to 600 mg/l phenol, 5.95 mg/l aniline, 17.85 mg/l quinoline, 197.43 mg/l m-cresol, and 85.57 mg/l toluene. When the ammonia nitrogen concentration was lower than 200 mg/l, the nitrification was stable. However, in the case of higher than 200 mg/l in the concentration of ammonia nitrogen, the removal efficiency of nitrogen was very low. Cyanide with concentration higher than 0.5 mg/l acted as a toxic material to microorganisms because it produced excessive foam and made the activity of microorganisms decrease. The threshold concentrations of organic materials such as m-cresol, toluene, quiline, and aniline that influence nitrification of microorganisms were 100 mg/l, 50 mg/l, and 200 mg/l, respectively. The change in the dilution ratio of raw wastewater and the additional amount of PAC did not make a big difference on the COD removal. On the other hand, the higher the dilution ratio of wastewater and additional amount of PAC increases, the higher the removal efficiency of ammonia nitrogen increases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Beckman, W. J.,“Design and Operation of Combined Carbon Oxidation-Nitrification Activated Sludge Plant,”J. Wat. Poll Con. Fed.,44, 1916(1972).

    CAS  Google Scholar 

  • Blum, D. J. W. and Speece, R. E., “A Database of Chemical Toxicity to Environmental Bacteria and Its Use in Interspecies Comparison and Correlation,”Res. J. Wat. Poll. Con. Fed.,63, 198 (1991).

    CAS  Google Scholar 

  • Boullanger, E. and Massol, L., “Etudes Sur les Microbes Nitrificateurs,”Ann. Inst. Pasteur,17, 492 (1903).

    CAS  Google Scholar 

  • Dowing, A. L. and Hopwood, A. P., “Some Observation on the Kinetics of Nitrifying Activated Sludge Plants,”Schweizerische Aeitschrift fur Hydrologie,26, 271 (1964).

    Article  Google Scholar 

  • Hockenbury, M. R. and Grady, P. L., “Inhibition of Nitrification Effects of Selected Organic Compounds,”J. Wat. Poll. Con. Fed.,49, 768 (1977).

    CAS  Google Scholar 

  • Kim, S. S., Ko, K. S., Kong, S. Y. and Jeon, H. D.,“Evaluation and Optimization for Wastewater Treatment Process of Coke Plant,” RIST Report of R & D, 2045A, 81 (1992).

  • Meiklejohn, J.,“Some Aspects of the Physiology of the Nitrifying Bacteria, Autotrophic Microorganism,” University Press, Cambridge, April, London (1954).

    Google Scholar 

  • Meyerhof, O.,“Beeinflussungen der Atmung des Nitratbildners durch Chemische Substanzen,”Pflug Arch. Ges. Physiol,164, 352 (1916).

    Google Scholar 

  • Neufeld, R. D., Hill, A. J. and Adekoya, L., “Phenol and Free Ammonia Inhibition toNitrosomonas Activity,”Wat. Res.,14, 196 (1980).

    Article  Google Scholar 

  • Painter, H. A., “A Review of Literature on Inorganic Nitrogen Metabolism in Microorganisms,”Wat. Res.,4, 393 (1970).

    Article  CAS  Google Scholar 

  • Park, S.-J., Kim, C. G., Yoon, T.-I. and Kim, D. W., “Evaluation of Increased Denitrification in an Anoxic Activated Sludge using Zeolite,”Korean J. Chem. Eng.,20, 492 (2003).

    CAS  Google Scholar 

  • Sawyer, C. N. and McCarty, P. L., “Chemistry for Sanitary Engineers,” 2nd Ed., McGraw-Hill, New York, NY(1967).

    Google Scholar 

  • Shnma, B. and Ahlert, R. C, “Nitrification and Nitrogen Removal,”Wat. Res.,11, 987 (1977).

    Google Scholar 

  • Skinner, E A. and Walker, N., “Growth of Nitrosomonas European in Batch and ContinuousCulture,”Arch. Mikrobiologie,38, 339 (1961).

    Article  Google Scholar 

  • Stamoudies, V. C. and Luthy, R G., “Determination of Biological Removal of Organic Constituents in Quench Water from High-BTU Coal-Gasification Pilot Plants,”Wat. Res.,14,1143 (1980).

    Article  Google Scholar 

  • Tomlinson, T. G., Boon, A. G. and Trotman, C. N. A., “Inhibition of Nitrification in the Activated Sludge Process of Sewage Disposal,”J. Applied Bact.,29, 266 (1966).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sang-Sik Kim.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kim, SS., Kim, HJ. Impact and threshold concentration of toxic materials in the stripped gas liquor on nitrification. Korean J. Chem. Eng. 20, 1103–1110 (2003). https://doi.org/10.1007/BF02706944

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02706944

Key words

Navigation