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Studies on the analyses for the scale of FGD process

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Abstract

During the period of preventive maintenance of the Ulsan power plant, the scale was sampled from riser pipes, sparger pipes and other important parts in the FGD facilities. Various analyses such as concentration analysis, surface morphology, and crystal structure have been performed on the scale sample. The riser pipe scale was a gypsum dihydrate form. The sparger pipe scale was different from two units, namely, gypsum dihydrate form was obtained from that of unit 6; on the other hand, 1 to 1 ratio of gypsum dihydrate form and anhydrate form was elucidated from that of unit 4. Next, the analyses of GCP spray nozzle head scale, gas-cooling zone scale, and BUF inlet duct scale were focused on the effect of base material. On the basis of the analytical results, we expect to elucidate the formation process of the scale, and finally to improve the FGD process.

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References

  • ASTM C471-76, “Chemical Analysis of Gypsum and Gypsum Products,” 1 (1985).

  • Brenner, I. B., Vats, S. and Zander, A. T., “New CCD Axially Viewed ICP Atomic Emission Spectrometer for Simultaneous Multi-element Geoanalysis. Determination of Major and Minor in Silicate Rocks,”J. Anal. Atomic Spectrometer,14, 1231 (1999).

    Article  CAS  Google Scholar 

  • Caroli, S., Forte, G. and Iamiceli, A. L., “ICP-AES and ICP-MS Quantification of Trace Elements in the Marine Macroalga Fucus sample, a New Candidate Certificate Reference Material,”Microchem. J.,62, 244 (1999).

    Article  CAS  Google Scholar 

  • Hanzel, D. S. and Laseke, B. A., “Construction Materials for Wet Scrubbers,” EPRI CS1-1736, Mar. (1980).

  • Kanicky, V. and Mermet, J.-M., “Selection of Internal Standards for the Determination of Major and Minor Elements in Silicate Rocks and Limestone by Laser Ablation Inductively Coupled Plasma Atomic Emission Spectrometry,”Applied Spectroscopy,51, 332 (1997).

    Article  CAS  Google Scholar 

  • Kim, K., Park, H., Lee, T. and Jeong, N., “Analysis of the Clinker Formed in Circulating Fludized Bed Boiler,”Analytical Science & Technology,13, 5 (2000a).

    CAS  Google Scholar 

  • Kim, K., Yang, S., Park, H. and Lim, C., “The Comparison of Analytical Methods for Gypsum and Gypsum Slurry,”Analytical Science & Technology,13, 158 (2000b).

    CAS  Google Scholar 

  • KS L9003-1996, “Method for Chemical Analysis of Gypsum,” KS, 1 (1996).

  • Lau, O.-W., Lam, L. and Luk, S.-F., “Analysis of Siliceous Materials and Coal by Atomic Absorption Spectrophotometry with Fusion for Sample Decomposition,”Talanta,51,1009 (2000).

    Article  CAS  Google Scholar 

  • Lee, S., Kim, K., Yang, S. and Jeong, N., “Analysis of the Scale Formed in GGH,”HWAHAK KONGHAK,38, 882 (2000).

    CAS  Google Scholar 

  • Mao, X., Chan, W. T. and Russo, R. E., “Influence of Sample Surface Condition on Chemical Analysis Using Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy,”Applied Spectroscopy,51, 1047 (1997).

    Article  CAS  Google Scholar 

  • Park, H., Kim, K., Yang, S. and Lee, G., “Studies on the Analytical Methods of Coal Ash,”J. Korean Chem. Soc.,44, 563 (2000).

    CAS  Google Scholar 

  • Reifenstein, A. P., Kahraman, H., Coin, C. D. A., Calos, N. I, Miller, G. and Uwins, P., “Behavior of Selected Minerials in an Improved Ash Fusion Test: Quarts, Potassium Feldspar, Kaolinite, Illite, Calcite, Dolomite, Siderite, Pyrite and Apatite,”Fuel,78,1449 (1999).

    Article  CAS  Google Scholar 

  • Rodushkin, I., Axelsson, M. D. and Burman, E., “Multieliment Analyses of Coal by ICP Techniques Using Solution Nebulization and Laser Ablation,”Talanta,51, 743 (2000).

    Article  CAS  Google Scholar 

  • Thompson, M., “Handbook of Inductively Coupled Plasma Spectrometry,” 2nd. Ed., Champman & Hall, 93 (1989).

  • Torigai, M., Ouyang, T., Iwashima, K., Osako, M. and Tanaka, M., “Studies on Microwave Digestion Procedure for the Simultaneous Multielement Determination of Arsenic, Antimony, Chromium, Cadmium, Nickel, and Lead in Municipal Waste Incineration Fly Ash by ICP-AES,”BUNSEKI KAGAKU,46, 401 (1997).

    CAS  Google Scholar 

  • Wei, R, Ikeda, K., Takeuchi, A., Jomen, K., Yamanaka., K., Sawatari, H. and Haraguchi, H., “Multielemental Determination of Major-toultratrace Elements in Lake Sediment Reference Materials by ICP-AES and ICP-MS,”BUNSEKI KAGAKU,48, 365 (1999).

    CAS  Google Scholar 

  • Wolfgang Gerhartz, “Calcium Sulfate,” Ullmann’s Encyclopedia of Industrial Chemistry, Deerfield Beach, FL, VCH,4A, 555 (1985).

    Google Scholar 

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Correspondence to Kyeongsook Kim.

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Kim, K., Yang, S., Song, H. et al. Studies on the analyses for the scale of FGD process. Korean J. Chem. Eng. 19, 46–51 (2002). https://doi.org/10.1007/BF02706873

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  • DOI: https://doi.org/10.1007/BF02706873

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