Abstract
Excess molar volumes (Vm E) of constituent binary mixtures of n-decane, n-dodecane, 1-decanol and 1-dodecanol which are the products of liquid phase oxidation of n-paraffins, have been measured experimentally as a function of composition x from density measurements at 308.15 K. The excess molar volumes of n-decane-n-dodecane system have negative deviation from the ideality while that of n-dodecane-1-decanol system have positive deviation. In the other systems, excess molar volume exhibits inversion in sign. Experimental data were successfully correlated with Redlich-Kister polynomial.
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Park, SJ., Gmehling, J. Excess molar volumes at the 308.15 K for constituent binaries of n-decane, n-dodecane, 1-decanol and 1-dodecanol. Korean J. Chem. Eng. 12, 152–155 (1995). https://doi.org/10.1007/BF02705639
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DOI: https://doi.org/10.1007/BF02705639