Abstract
The combustion synthesis (CS) of materials is an advanced approach in powder metallurgy. The number of products synthesized by CS has increased rapidly during recent years and currently exceeds 1,000 different compounds. The same features, such as high temperatures and rates, self-sustained manner of microstructure formation in non-equilibrium conditions, that make CS an attractive technology also define difficulties to study the nature and mechanisms of this process, which in turn are essential to control the properties of the synthesized materials. In this survey paper, we present results of our recent work both in fundamental studies of mechanisms for rapid reaction wave propagation in heterogeneous media and in using the CS approach to synthesize different types of advanced materials, including bio-alloys and nano-sized powders.
Similar content being viewed by others
References
Deshpande, K., Mukasyan, A. S. and Varma, A., “Aqueous Combustion Synthesis of Strontium-Doped Lanthanum Chromate Ceramics,”J. Am. Ceram. Soc.,86, 1149 (2003).
Deshpande, K., Mukasyan, A. S. and Varma, A., “Synthesis of Iron Oxide Nanopowders by Combustion Approach: Reaction Mechanism and Properties,”Chem. Mater. (2004, in review).
Hwang, S., Mukasyan, A. S. and Varma, A., “Mechanisms of Combustion Wave Propagation in Heterogeneous Reaction Systems,”Combust. Flame,115, 354 (1998).
Hwang, S., Mukasyan, A. S., Rogachev, A. S. and Varma, A., “Combustion Wave Microstructure in Gas-Solid Systems: Experiments and Theory,”Combust. Sci. Tech.,123, 165 (1997).
Kharatyan, S. L., Chatilyan, H. A., Mukasyan, A. S., Simonetti, D.A. and Varma, A., “Influence of Heating Rate on Kinetics of Rapid High-Temperature Reactions in Condensed Heterogeneous Media: Mo-Si System,”AIChE J. (2004, in press).
Lau, C., Mukasyan, A. S. and Varma, A., “Materials Synthesis by Reduction-Type Combustion Reaction: Influence of Gravity,”Proc. Combust. Inst.,29, 1101 (2002).
Lau, C., Mukasyan, A. S. and Varma, A., “Reaction and Phase Separation Mechanisms during Synthesis of Alloys by Thermite Type Combustion Reactions,”J. Mat. Res.,18, 121 (2003).
Lau, C., Mukasyan, A. S., Pelekh, A. and Varma, A., “Mechanistic Studies in Combustion Synthesis of NiAl-TiB2 Composites: Effects of Gravity,”J. Mater. Res.,16, 1614 (2001).
Li, B., Mukasyan, A. S. and Varma, A., “Combustion Synthesis of CoCr Mo (F-75) Implant Alloys: Microstructure and Properties,”Mater. Res. Inov,7, 245 (2003).
Merzhanov, A. G., “Self-Propagating High-Temperature Synthesis: Twenty Years of Search and Findings,” In Combustion and Plasma Synthesis of High-Temperature Materials, edited by Z.A. Munir and J. B. Holt, New York, VCH Publishers, 1 (1990).
Moore, J. J. and Feng, H. J., “Combustion Synthesis of Advanced Materials,”Prog. Mater. Sci.,39, 243 (1995).
Mukasyan, A. S., Costello, C., Sherlock, K. P., Lafarga, D. and Varma, A., “Perovskite Membranes by Aqueous Combustion Synthesis: Synthesis and Properties,”Sep. & Purif. Tech.,25, 117 (2001b).
Mukasyan, A. S., Hwang, S., Rogachev, A. S., Sytchev, A. E., Merzhanov, A.G. and Varma, A., “Combustion Wave Microstructure in Heterogeneous Gasless Systems,”Combust. Sci. Tech.,115, 335 (1996).
Mukasyan, A. S., Lau, C. and Varma, A., Review: “Influence of Gravity on Combustion Synthesis of Advanced Materials,”AIAA J. (2004, in press).
Mukasyan, A. S., Lau, C. and Varma, A., “Gasless Combustion of Aluminum Particles Clad by Nickel,”Combust. Sci. Tech.,170, 67 (2001a).
Mukasyan, A. S., Marasia, J.A., Filimonov, I.A. and Varma, A., “The Role of Infiltration on Spin Combustion in Gas-Solid Systems,”Combust. Flame,122, 368 (2000b).
Mukasyan, A. S., Pelekh, A. and Varma, A., “Combustion Synthesis in Gasless Systems under Microgravity Conditions,”J. Mater. Synth. Proc.,5, 391 (1997a).
Mukasyan, A. S., Pelekh, A., Varma, A., Rogachev, A. S. and Jenkins, A., “The Effects of Gravity on Combustion Synthesis in Heterogeneous Gasless Systems,”AIAA J.,35, 1821 (1997b).
Mukasyan, A. S., Rogachev, A. S. and Varma, A., “Mechanism of Reaction Wave Propagation during Combustion Synthesis of Advanced Materials,”Chem. Eng. Sci.,54, 3357 (1999a).
Mukasyan, A. S., Rogachev, A. S. and Varma, A., “Microscopic Mechanisms of Pulsating Combustion in Gasless Systems,”AIChE J.,45, 2580 (1999b).
Mukasyan, A. S., Rogachev, A. S., Mercedes, M. and Varma, A., “Microstructural Correlations between Reaction Medium and Combustion Wave Propagation in Heterogeneous Systems,”Chem. Eng. Sci. (2004, in review).
Mukasyan, A. S., Rogachev, A. S. and Varma, A., “Microstructural Mechanism of Combustion in Heterogeneous Reaction Media,”Proc. Combust. Inst.,28, 1413 (2000a).
Munir, Z. A. and Anselmi-Tamburini, U., “Self-Propagating Exothermic Reactions: The Synthesis of High-Temperature Materials by Combustion,”Mater. Sci. Reports,3, 277 (1989).
Patil, K. C., Aruna, S. T. and Mimani, T., “Combustion Synthesis: An Update,”Curr. Opin. Solid State & Mater. Sci.,6, 507 (2002).
Pelekh, A., Mukasyan, A. S. and Varma, A., “Electrothermography Apparatus for Kinetics of Rapid High-Temperature Reactions,”Rev. Sci. Instrum.,71, 220 (2000).
Pelekh, A., Mukasyan, A. S. and Varma, A., “Kinetics of Rapid High-Temperature Reactions: Titanium-Nitrogen System,”Ind. Eng. Chem. Res.,38, 793 (1999).
Rogachev, A. S., Mukasyan, A. S. and Varma, A., “Thermal Explosion Modes in Gasless Heterogeneous Systems,”J. Mater. Synth. Proc.,10, 29 (2002).
Rogachev, A. S., Shugaev, V. A., Kachelmayer, C. R. and Varma, A., “Mechanisms of Structure Formation During Combustion Synthesis of Materials,”Chem. Eng. Sci.,49, 4949 (1994).
Thiers, L., Leitenberger, B., Mukasyan, A. S. and Varma, A., “Influence of Preheating Rate on Kinetics of High-Temperature Gas-Solid Reactions,”AIChE J.,46, 2518 (2000).
Thiers, L., Mukasyan, A. S. and Varma, A., “Thermal Explosion in Ni-Al System: Influence of Reaction Medium Microstructure,”Combust. Flame,131, 198 (2002).
Thiers, L., Mukasyan, A. S., Pelekh, A. and Varma, A., “Kinetics of High-Temperature Reaction in Titanium-Nitrogen System: Nonisothermal Conditions,”Chem. Eng. J.,82, 303 (2001).
Varma, A. and Mukasyan, A. S., “Combustion Synthesis of Advanced Materials”, in ASM Handbook,”Powder Metal Technologies and Applications,7, 523 (1998).
Varma, A., “Form from Fire,”Scientific American,283(2), 58 (2000).
Varma, A., Li, B. and Mukasyan, A., “Novel Synthesis of Orthopaedic Implant Materials,”Adv. Eng. Mater.,4, 482 (2002).
Varma, A., Mukasyan, A. S. and Hwang, S., “Dynamics of Self-Propagating Reactions in Heterogeneous Media: Experiments and Model,”Chem. Eng. Sci.,56, 1459 (2001).
Varma, A., Rogachev, A. S., Mukasyan, A. S. and Hwang, S., “Complex Behavior of Self-Propagating Reaction Waves in Heterogeneous Media,”Proc. Natl. Acad. Sci. USA,95, 11053 (1998b).
Varma, A., Rogachev, A. S., Mukasyan, A. S. and Hwang, S., Review: “Combustion Synthesis of Advanced Materials: Principles and Applications,”Advances in Chemical Engineering,24, 79 (1998a).
Author information
Authors and Affiliations
Corresponding author
Additional information
°This paper is dedicated to Professor Hyun-Ku Rhee on the occasion of his retirement from Seoul National University.
Rights and permissions
About this article
Cite this article
Varma, A., Mukasyan, A.S. Combustion synthesis of advanced materials: Fundamentals and applications. Korean J. Chem. Eng. 21, 527–536 (2004). https://doi.org/10.1007/BF02705444
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02705444